The Journal of organic chemistry

Synthesis of two naphthoquinone antibiotics, dehydroherbarin and 6-deoxybostrycoidin

B Kesteleyn, N De Kimpe

Index: Aldersley, Michael F.; Dean, Francis M.; Nayyir-Mazhir, Rassoul Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 8 p. 1753 - 1757

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Citation Number: 44

Abstract

... The Journal of Organic ... The reactive methide 17 in a Michael-type addition with a second equivalent of pyridinium ylide affords compound 18 ... On the other hand, reaction of naphthoquinone 23 with a solution of 7 M ammonia in methanol afforded a 1:1 mixture of dehydroherbarin ...