Bimetallic reactivity. Preparations, properties and structures of complexes formed by unsymmetrical binucleating ligands bearing 4-and 6-coordinate sites supported …

…, M Lam, B Rhatigan, AL Rheingold, CJ Qin…

Index: Incarvito; Lam; Rhatigan; Rheingold; Jin Qin; Gavrilova; Bosnich Journal of the Chemical Society, Dalton Transactions, 2001 , # 23 p. 3478 - 3488

Full Text: HTML

Citation Number: 32

Abstract

Four binucleating ligands which potentially could provide bimetallic complexes bearing 5- and 6-coordinate sites have been prepared. These ligands, which have alkoxide bridging groups, can be regarded as more elaborate versions of binucleating ligands which have tridentate chelates on each side of the alkoxy bridge. Unlike these previous, less complex ligands, the present series of binucleating ligands have a strong tendency to form ...