Tetrahedron

Preparation of N-arylamines from 2-oxo-7-azobicyclo [4.1. 0] heptanes

MT Barros, SS Dey, CD Maycock, P Rodrigues

Index: Barros, M. Teresa; Dey, Suvendu S.; Maycock, Christopher D.; Rodrigues, Paula Tetrahedron, 2012 , vol. 68, # 31 p. 6263 - 6268

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Abstract

The importance of nitrogen-containing compounds, 1 as is evident from their wide occurrence in nature and broad application in chemistry, biology, and material sciences, has for a long time induced chemists to actively investigate methods to form C–N bonds. Commonly used methods, such as reductive amination of carbonyl groups, 2 Ullmann reaction and its modifications, 3 Pd-catalyzed Buchwald–Hartwig amination of aryl halides, 4 and direct ...