Synthesis

A practical large-scale access to 1, 6-anhydro-β-D-hexopyranoses by a solid-supported solvent-free microwave-assisted procedure

…, RM de Figueiredo, A Olesker, J Cleophax

Index: Bailliez, Vincent; De Figueiredo, Renata M.; Olesker, Alain; Cleophax, Jeannine Synthesis, 2003 , # 7 p. 1015 - 1017

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Citation Number: 13

Abstract

Abstract Microwave irradiation of 6-O-tosyl or 2, 6-di-O-tosyl peracetylated hexopyranoses absorbed on basic alumina in a dry medium afforded the corresponding 1, 6-anhydro-β-d- hexopyranoses. A direct access to 1, 6: 3, 4-dianhydro-β-d-altropyranose (16) from d- glucose is also described.