e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Journal of organometallic chemistry

Polygermanes precurseurs d'especes du germanium a coordinance non usuelle

P Riviere, A Castel, J Satgé, D Guyot

Index: Riviere, P.; Castel, A.; Satge, J.; Guyot, D. Journal of Organometallic Chemistry, 1984 , vol. 264, # 1-2 p. 193 - 206

Full Text: HTML

Citation Number: 27

Abstract

Abstract Several thermal or photochemical α-elimination reactions of functional polygermanes lead to germylenes, R 2 Ge. Photolysis of polygermanes, cyclopolygermanes and polygermylmercury compounds and also hydrogen abstraction from various organohydropolygermanes using t-BuO., lead to the formation of polymetallated chains containing one or two germanium-centered radicals.

Digermane, 1-chloro-1,1,2,2-tetraethyl Structure

Digermane, 1-ch...

Di-tert-butyl peroxide Structure

Di-tert-butyl p...

~30%

1,1,2,2,3,3,4,4-octaethyltetragermetane Structure

1,1,2,2,3,3,4,4...

1,4-dichloro-1,1,2,2,3,3,4,4-octaethyltetragermane Structure

1,4-dichloro-1,...

Detail Learn More

1-chloro-1,1,2,2,3,3-hexaethyltrigermane Structure

1-chloro-1,1,2,...

Di-tert-butyl peroxide Structure

Di-tert-butyl p...

~66%

1,1,2,2,3,3,4,4-octaethyltetragermetane Structure

1,1,2,2,3,3,4,4...

1,4-dichloro-1,1,2,2,3,3,4,4-octaethyltetragermane Structure

1,4-dichloro-1,...

Detail Learn More

N/A Structure

~6%

Digermane, 1-chloro-1,1,2,2-tetraethyl Structure

Digermane, 1-ch...

1-chloro-1,1,2,2,3,3-hexaethyltrigermane Structure

1-chloro-1,1,2,...

chloro(diethyl)germanium,diethylgermanium Structure

chloro(diethyl)...

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Digermane, 1-chloro-1,1,2,2-tetraethyl Structure

Digermane, 1-ch...

Di-tert-butyl peroxide Structure

Di-tert-butyl p...

~8%

1,4-dichloro-1,1,2,2,3,3,4,4-octaethyltetragermane Structure

1,4-dichloro-1,...

chloro(diethyl)germane Structure

chloro(diethyl)...

Detail Learn More

1,1,2,2,3,3,4,4-octaethyltetragermetane Structure

1,1,2,2,3,3,4,4...

2,3-DIMETHYL-1,3-BUTADIENE Structure

2,3-DIMETHYL-1,...

~%

1,1,3,3,5,5-hexaethylcyclotrigermoxane Structure

1,1,3,3,5,5-hex...

N/A Structure

Detail Learn More

Trigermane, 2-chloro-1,1,1,2,3,3,3-heptaphenyl Structure

Trigermane, 2-c...

2,3-DIMETHYL-1,3-BUTADIENE Structure

2,3-DIMETHYL-1,...

~3%

1H-Germole, 2,5-dihydro-3,4-dimethyl-1-phenyl-1-(triphenylgermyl) Structure

1H-Germole, 2,5...

Digermane,1,1,1,2,2,2-hexaphenyl Structure

Digermane,1,1,1...

Detail Learn More

Digermane, 1,1-dichloro-1,2,2,2-tetraphenyl Structure

Digermane, 1,1-...

2,3-DIMETHYL-1,3-BUTADIENE Structure

2,3-DIMETHYL-1,...

~4%

Digermane,1,1,1,2,2,2-hexaphenyl Structure

Digermane,1,1,1...

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1,1,2,2-tetrachlorodiphenyldigermane Structure

1,1,2,2-tetrach...

2,3-DIMETHYL-1,3-BUTADIENE Structure

2,3-DIMETHYL-1,...

~70%

Chlorotriphenylgermane Structure

Chlorotriphenyl...

1-Chloro-3,4-dimethyl-1-phenyl-2,5-dihydro-1H-germole Structure

1-Chloro-3,4-di...

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1,1,2,2-tetrachlorodiphenyldigermane Structure

1,1,2,2-tetrach...

2,3-DIMETHYL-1,3-BUTADIENE Structure

2,3-DIMETHYL-1,...

~14%

Trichloro(phenyl)germane Structure

Trichloro(pheny...

1-Chloro-3,4-dimethyl-1-phenyl-2,5-dihydro-1H-germole Structure

1-Chloro-3,4-di...

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Digermane, 1,1-dichloro-1,2,2,2-tetraphenyl Structure

Digermane, 1,1-...

2,3-DIMETHYL-1,3-BUTADIENE Structure

2,3-DIMETHYL-1,...

~32%

Triphenylgermanium hydride Structure

Triphenylgerman...

Chlorotriphenylgermane Structure

Chlorotriphenyl...

Detail Learn More

Digermane, 1,1-dichloro-1,2,2,2-tetraphenyl Structure

Digermane, 1,1-...

2,3-DIMETHYL-1,3-BUTADIENE Structure

2,3-DIMETHYL-1,...

~5%

Triphenylgermanium hydride Structure

Triphenylgerman...

Chlorotriphenylgermane Structure

Chlorotriphenyl...

Detail Learn More

Trigermane, 2-chloro-1,1,1,2,3,3,3-heptaphenyl Structure

Trigermane, 2-c...

2,3-DIMETHYL-1,3-BUTADIENE Structure

2,3-DIMETHYL-1,...

~2%

1H-Germole, 2,5-dihydro-3,4-dimethyl-1-phenyl-1-(triphenylgermyl) Structure

1H-Germole, 2,5...

Digermane,1,1,1,2,2,2-hexaphenyl Structure

Digermane,1,1,1...

Detail Learn More

Digermane, 1-chloro-1,1,2,2-tetraethyl Structure

Digermane, 1-ch...

ETHYLMAGNESIUM BROMIDE Structure

ETHYLMAGNESIUM ...

~46%

diethyl-hydrido-germanium; triethylgermanium Structure

diethyl-hydrido...

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Digermane, 1,1-dichloro-1,2,2,2-tetraphenyl Structure

Digermane, 1,1-...

2,3-DIMETHYL-1,3-BUTADIENE Structure

2,3-DIMETHYL-1,...

~3%

Triphenylgermanium hydride Structure

Triphenylgerman...

Chlorotriphenylgermane Structure

Chlorotriphenyl...

Detail Learn More

Digermane, 1,1-dichloro-1,2,2,2-tetraphenyl Structure

Digermane, 1,1-...

2,3-DIMETHYL-1,3-BUTADIENE Structure

2,3-DIMETHYL-1,...

~2%

Triphenylgermanium hydride Structure

Triphenylgerman...

Chlorotriphenylgermane Structure

Chlorotriphenyl...

Detail Learn More

N/A Structure

Dimethyl disulfide Structure

Dimethyl disulfide

~0%

Trigermane, 1,1,2,2,3,3-hexaethyl-1,3-bis(methylthio) Structure

Trigermane, 1,1...

Digermane, 1,1,2,2-tetraethyl-1,2-bis(methylthio) Structure

Digermane, 1,1,...

Detail Learn More

Dimethyl disulfide Structure

Dimethyl disulfide

Digermane, 1,1-diethyl-1-(methylthio)-2,2,2-triphenyl Structure

Digermane, 1,1-...

~13%

Digermane, 1,1,2,2-tetraethyl-1,2-bis(methylthio) Structure

Digermane, 1,1,...

Thiomethyltriphenylgerman Structure

Thiomethyltriph...

Detail Learn More

Trigermane, 1,1,2,2,3,3-hexaethyl-1,3-bis(methylthio) Structure

Trigermane, 1,1...

Dimethyl disulfide Structure

Dimethyl disulfide

~3%

Digermane, 1,1,2,2-tetraethyl-1,2-bis(methylthio) Structure

Digermane, 1,1,...

diethyl-bis(methylsulfanyl)germane Structure

diethyl-bis(met...

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1,1,2,2,3,3,4,4-octaethyltetragermetane Structure

1,1,2,2,3,3,4,4...

Dimethyl disulfide Structure

Dimethyl disulfide

~%

Trigermane, 1,1,2,2,3,3-hexaethyl-1,3-bis(methylthio) Structure

Trigermane, 1,1...

Tetragermane, 1,1,2,2,3,3,4,4-octaethyl-1,4-bis(methylthio) Structure

Tetragermane, 1...

Detail Learn More

1,1,2,2,3,3,4,4,5,5-decaethylpentagermolane Structure

1,1,2,2,3,3,4,4...

Dimethyl disulfide Structure

Dimethyl disulfide

~%

Trigermane, 1,1,2,2,3,3-hexaethyl-1,3-bis(methylthio) Structure

Trigermane, 1,1...

Tetragermane, 1,1,2,2,3,3,4,4-octaethyl-1,4-bis(methylthio) Structure

Tetragermane, 1...

Detail Learn More

chloro-diphenyl-germanium Structure

chloro-diphenyl...

2,3-DIMETHYL-1,3-BUTADIENE Structure

2,3-DIMETHYL-1,...

~18%

3,4-dimethyl-1,1-diphenyl-2,5-dihydrogermole Structure

3,4-dimethyl-1,...

Dichloro(diphenyl)germane Structure

Dichloro(diphen...

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1,2-bis(methylthio)-1,1,2,2-tetraphenyldigermane Structure

1,2-bis(methylt...

2,3-DIMETHYL-1,3-BUTADIENE Structure

2,3-DIMETHYL-1,...

~10%

bis(methylthio)diphenylgermane Structure

bis(methylthio)...

3,4-dimethyl-1,1-diphenyl-2,5-dihydrogermole Structure

3,4-dimethyl-1,...

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Ph2ClGeGePh3 Structure

2,3-DIMETHYL-1,3-BUTADIENE Structure

2,3-DIMETHYL-1,...

~0%

Chlorotriphenylgermane Structure

Chlorotriphenyl...

3,4-dimethyl-1,1-diphenyl-2,5-dihydrogermole Structure

3,4-dimethyl-1,...

Learn More

chloro-diphenyl-germanium Structure

chloro-diphenyl...

2,3-DIMETHYL-1,3-BUTADIENE Structure

2,3-DIMETHYL-1,...

~0%

Chlorotriphenylgermane Structure

Chlorotriphenyl...

3,4-dimethyl-1,1-diphenyl-2,5-dihydrogermole Structure

3,4-dimethyl-1,...

Detail Learn More