Journal of Organometallic Chemistry

Selective mono-and di-allylation and allenylation of chlorosilanes using indium

Z Li, C Yang, H Zheng, H Qiu, G Lai

Index: Li, Zhifang; Yang, Chenjun; Zheng, Hongfang; Qiu, Huayu; Lai, Guoqiao Journal of Organometallic Chemistry, 2008 , vol. 693, # 25 p. 3771 - 3779

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Abstract

Allyl and allenyl groups have been introduced into silicon systems by the allylation and allenylation of chlorosilanes using allyl bromide or propargyl bromide with indium. The allylation of chlorosilanes afforded a variety of aryl, aralkyl, and alkenyl substituted allylsilanes. By applying this method, the reactions of 1-bromo-3-methylbut-2-ene, 3-bromo- 2-methylprop-1-ene and 3-bromobut-1-ene with chlorosilanes also proceed smoothly to ...