Inter??and Intramolecular Palladium??Catalyzed Allyl Cross??Coupling Reactions Using Allylindium Generated In Situ from Allyl Acetates, Indium, and Indium Trichloride

D Seomoon, K Lee, H Kim…

Index: Seomoon, Dong; Lee, Kooyeon; Kim, Hyunseok; Lee, Phil Ho Chemistry - A European Journal, 2007 , vol. 13, # 18 p. 5197 - 5206

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Citation Number: 40

Abstract

Abstract Inter-and intramolecular palladium-catalyzed allyl cross-coupling reactions using allylindium generated in situ by treatment of allyl acetates with indium and indium trichloride in the presence of Pd 0 catalyst and nBuNMe 2 in DMF were successfully demonstrated. Allylindium species generated in situ by reductive transmetalation of π-allylpalladium (II) complexes, obtained from a variety of allyl acetates in the presence of Pd 0 catalyst ...