2-Naphthyl trifluoromethanesulfonate structure
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Common Name | 2-Naphthyl trifluoromethanesulfonate | ||
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CAS Number | 3857-83-8 | Molecular Weight | 276.23200 | |
Density | 1.493g/cm3 | Boiling Point | 343.8ºC at 760 mmHg | |
Molecular Formula | C11H7F3O3S | Melting Point | 30-32ºC(lit.) | |
MSDS | Chinese USA | Flash Point | >230 °F | |
Symbol |
GHS05 |
Signal Word | Danger |
Name | naphthalen-2-yl trifluoromethanesulfonate |
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Synonym | More Synonyms |
Density | 1.493g/cm3 |
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Boiling Point | 343.8ºC at 760 mmHg |
Melting Point | 30-32ºC(lit.) |
Molecular Formula | C11H7F3O3S |
Molecular Weight | 276.23200 |
Flash Point | >230 °F |
Exact Mass | 276.00700 |
PSA | 51.75000 |
LogP | 4.14900 |
Index of Refraction | 1.56 |
Symbol |
GHS05 |
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Signal Word | Danger |
Hazard Statements | H314 |
Precautionary Statements | P280-P305 + P351 + P338-P310 |
Personal Protective Equipment | Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges |
Hazard Codes | C: Corrosive; |
Risk Phrases | 34 |
Safety Phrases | 22-26-27-36/37/39-45 |
RIDADR | UN 3261 8/PG 2 |
HS Code | 2906299090 |
~96% 2-Naphthyl trif... CAS#:3857-83-8 |
Literature: Brimble, Margaret A.; Lai, Michelle Y.H. Organic and Biomolecular Chemistry, 2003 , vol. 1, # 12 p. 2084 - 2095 |
~99% 2-Naphthyl trif... CAS#:3857-83-8 |
Literature: Boisnard, Sabine; Chastanet, Jaqueline; Zhu, Jieping Tetrahedron Letters, 1999 , vol. 40, # 42 p. 7469 - 7472 |
~94% 2-Naphthyl trif... CAS#:3857-83-8 |
Literature: Jean, Mickael; Renaulty, Jacques; Uriac, Philippe; Capet, Marc; Van De Weghe, Pierre Organic Letters, 2007 , vol. 9, # 18 p. 3623 - 3625 |
~% 2-Naphthyl trif... CAS#:3857-83-8 |
Literature: DAIICHI PHARMACEUTICAL CO., LTD. Patent: EP949238 A1, 1999 ; |
~72% 2-Naphthyl trif... CAS#:3857-83-8 |
Literature: Effenberger; Mack Tetrahedron Letters, 1970 , p. 3947 |
~% 2-Naphthyl trif... CAS#:3857-83-8 |
Literature: Gmelin Handbook: F: PerFHalOrg.2, 1.3.4, page 137 - 166 |
~% 2-Naphthyl trif... CAS#:3857-83-8 |
Literature: Hendrickson,J.B.; Bergeron,R. Tetrahedron Letters, 1973 , # 46 p. 4607 - 4610 |
Precursor 10 | |
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DownStream 10 | |
HS Code | 2906299090 |
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Summary | 2906299090 other aromatic alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0% |
Palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides.
J. Am. Chem. Soc. 132 , 14076, (2010) The palladium-catalyzed conversion of aryl and vinyl triflates to aryl and vinyl halides (bromides and chlorides) has been developed using dialkylbiaryl phosphine ligands. A variety of aryl, heteroary... |
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Regiochemical control and suppression of double bond isomerization in the Heck arylation of 1-(methoxycarbonyl)-2, 5-dihydropyrrole. Sonesson C, et al.
J. Org. Chem. 61(14) , 4756-4763, (1996)
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Influence of the catalyst on the Pd0-mediated reactions of BrZnCH(CH3) COOtBu with vinyl and aryl triflates. Orsini F, et al.
J. Organomet. Chem. 367(3) , 375-382, (1989)
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2-naphthol triflate |
MFCD00192341 |
2-naphthyl triflate |
2-Naphthyl Trifluoromethanesulfonate |
Trifluoromethanesulfonic Acid 2-Naphthyl Ester |
naphthyl-OTf |
trifluoromethanesulfonic acid naphthalen-2-yl ester |