2-Naphthyl trifluoromethanesulfonate

Modify Date: 2024-01-10 19:02:12

2-Naphthyl trifluoromethanesulfonate Structure
2-Naphthyl trifluoromethanesulfonate structure
Common Name 2-Naphthyl trifluoromethanesulfonate
CAS Number 3857-83-8 Molecular Weight 276.23200
Density 1.493g/cm3 Boiling Point 343.8ºC at 760 mmHg
Molecular Formula C11H7F3O3S Melting Point 30-32ºC(lit.)
MSDS Chinese USA Flash Point >230 °F
Symbol GHS05
GHS05
Signal Word Danger

 Names

Name naphthalen-2-yl trifluoromethanesulfonate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.493g/cm3
Boiling Point 343.8ºC at 760 mmHg
Melting Point 30-32ºC(lit.)
Molecular Formula C11H7F3O3S
Molecular Weight 276.23200
Flash Point >230 °F
Exact Mass 276.00700
PSA 51.75000
LogP 4.14900
Index of Refraction 1.56

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes C: Corrosive;
Risk Phrases 34
Safety Phrases 22-26-27-36/37/39-45
RIDADR UN 3261 8/PG 2
HS Code 2906299090

 Synthetic Route

~96%

2-Naphthyl trifluoromethanesulfonate Structure

2-Naphthyl trif...

CAS#:3857-83-8

Literature: Brimble, Margaret A.; Lai, Michelle Y.H. Organic and Biomolecular Chemistry, 2003 , vol. 1, # 12 p. 2084 - 2095

~99%

2-Naphthyl trifluoromethanesulfonate Structure

2-Naphthyl trif...

CAS#:3857-83-8

Literature: Boisnard, Sabine; Chastanet, Jaqueline; Zhu, Jieping Tetrahedron Letters, 1999 , vol. 40, # 42 p. 7469 - 7472

~94%

2-Naphthyl trifluoromethanesulfonate Structure

2-Naphthyl trif...

CAS#:3857-83-8

Literature: Jean, Mickael; Renaulty, Jacques; Uriac, Philippe; Capet, Marc; Van De Weghe, Pierre Organic Letters, 2007 , vol. 9, # 18 p. 3623 - 3625

~%

2-Naphthyl trifluoromethanesulfonate Structure

2-Naphthyl trif...

CAS#:3857-83-8

Literature: DAIICHI PHARMACEUTICAL CO., LTD. Patent: EP949238 A1, 1999 ;

~72%

2-Naphthyl trifluoromethanesulfonate Structure

2-Naphthyl trif...

CAS#:3857-83-8

Literature: Effenberger; Mack Tetrahedron Letters, 1970 , p. 3947

~%

2-Naphthyl trifluoromethanesulfonate Structure

2-Naphthyl trif...

CAS#:3857-83-8

Literature: Gmelin Handbook: F: PerFHalOrg.2, 1.3.4, page 137 - 166

~%

2-Naphthyl trifluoromethanesulfonate Structure

2-Naphthyl trif...

CAS#:3857-83-8

Literature: Hendrickson,J.B.; Bergeron,R. Tetrahedron Letters, 1973 , # 46 p. 4607 - 4610

 Customs

HS Code 2906299090
Summary 2906299090 other aromatic alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

 Articles3

More Articles
Palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides.

J. Am. Chem. Soc. 132 , 14076, (2010)

The palladium-catalyzed conversion of aryl and vinyl triflates to aryl and vinyl halides (bromides and chlorides) has been developed using dialkylbiaryl phosphine ligands. A variety of aryl, heteroary...

Regiochemical control and suppression of double bond isomerization in the Heck arylation of 1-(methoxycarbonyl)-2, 5-dihydropyrrole. Sonesson C, et al.

J. Org. Chem. 61(14) , 4756-4763, (1996)

Influence of the catalyst on the Pd0-mediated reactions of BrZnCH(CH3) COOtBu with vinyl and aryl triflates. Orsini F, et al.

J. Organomet. Chem. 367(3) , 375-382, (1989)

 Synonyms

2-naphthol triflate
MFCD00192341
2-naphthyl triflate
2-Naphthyl Trifluoromethanesulfonate
Trifluoromethanesulfonic Acid 2-Naphthyl Ester
naphthyl-OTf
trifluoromethanesulfonic acid naphthalen-2-yl ester
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