The Journal of chemical physics

The isomerization of 1??methylcyclopropene: A multichannel unimolecular reaction induced by overtone excitation

JE Baggott, DW Law

Index: Baggott, J. E.; Law, D. W. Journal of Chemical Physics, 1988 , vol. 88, # 2 p. 900 - 906

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Citation Number: 7

Abstract

The distribution of products resulting from the isomerization of gas phase 1?? methylcyclopropene (1) induced by C–H stretch overtone excitation has been studied in a search for mode specific effects. Quantum yields for the disappearance of 1 have been determined as a function of the total pressure of a mixture of 1 and methylenecyclopropane and of the added bath gases SF6 and Ar using a combination of intracavity dye ...