Inorganic Chemistry

Rate-determining t2g-t2g electron transfer: reaction of (3-formylpentane-2, 4-dionato) bis (pentane-2, 4-dionato) ruthenium (III) with titanium (III) and formation of ( …

BH Berrie, JE Earley

Index: Berrie, Barbara H.; Earley, Joseph E. Inorganic Chemistry, 1984 , vol. 23, p. 774 - 778

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Citation Number: 9

Abstract

Ti (II1) in a reaction that involves two relaxations with rate constants k; k [Ti (III)] h [H+]-'+ k'and k,'z 20 Ml sI, where h=[H+]/([H+]+ 0.004 M), k= 2 X lo2 M-'sl, and k'= 750 MI sl. These results are interpreted as indicating rate-determining electron transfer within a deprotonated binuclear intermediate.