Phosphorus, Sulfur, and Silicon

Substitution Reactions of Mono-and Trichloro Acetic Acids with Ammonium Dialkyl (Alkylene) Dithiophosphates

N Harkut, PN Nagar

Index: Harkut, Neelam; Nagar, Padam N. Phosphorus, Sulfur and Silicon and the Related Elements, 2007 , vol. 182, # 1 p. 219 - 226

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Abstract

A reaction of mono-and trichloro acetic acid with ammonium salts of alkylene (dialkyl) dithiophosphate;[S2NH4; G=─ CH2CH2CHMe─,─ C (Me) 2C (Me) 2─,─ CH2C (Me) 2CH2─, and─ C (Me) 2CH2CHMe─;(RO) 2PS2-NH4; and R= C2H5, C3H7, i-C3H7;] in a 1: 1 molor ratio in refluxing benzene solution yields low melting solids and light-yellow oily liquids of the type [(RO) 2PS2R'and S2R′, where R′= CH2COOH and Cl2CCOOH], ...