Palladium??Catalyzed Methoxylation of Aromatic Chlorides with Borate Salts

GL Tolnai, B Pethő, P Králl…

Index: Tolnai, Gergely L.; Petho, Balint; Krall, Peter; Novaka, Zoltan Advanced Synthesis and Catalysis, 2014 , vol. 356, # 1 p. 125 - 129

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Citation Number: 7

Abstract

Abstract: Herein we disclose a simple palladiumcatalyzed transformation for the methoxylation of aromatic chlorides with tetramethoxyborate salts. The procedure provides a new and efficient synthetic tool for the introduction of a methoxy group into aromatic systems. In addition, the reaction can be achieved using a wide range of aromatic and heteroACHTUNGTRENNUNGaromatic chlorides, the cheapest class of halides. Keywords ...