Reaction of dialkylchloroboranes with ethyl diazoacetate at low temperatures. Facile two-carbon homologation under exceptionally mild conditions

HC Brown, MM Midland, AB Levy

Index: Journal of the American Chemical Society, , vol. 94, p. 3662 - 3664

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Citation Number: 34

Abstract

... Our recent discovery of the increased reactivity toward organic azides of dialkylchloroboranes as compared to trialkylboranes led us to investigate the related reaction between dialkylchloroboranes and ethyl diazoacetate. ... Journal of the American Chemical Society 94:lO ...