Silylene-to-silanone thermal isomerization

L Linder, A Revis, TJ Barton

Index: Linder,L.; Revis,A.; Barton,T.J. Journal of the American Chemical Society, 1986 , vol. 108, p. 2742

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Citation Number: 9

Abstract

PPh,. Therefore, while kco* apparently reflects large qualitative differences in reactivity, it appears not to be sensitive to small differences in closely related compounds. On the basis of the above studies, one must conclude that it is not clear whether kco* is related to kinetic or thermodynamic factors and that kco* is useful primarily for predictions when fairly large differences in reactivity are involved. Conclusions Results of this paper show that kco* is a very useful parameter ...