Analytica Chimica Acta 2010-09-23

Simultaneous determination of electroactive and non-electroactive food preservatives by novel capillary electrophoresis with amperometric detection.

Weiyu Wang, Yiping Wang, Junbo Zhang, Qingcui Chu, Jiannong Ye

Index: Anal. Chim. Acta 678(1) , 39-43, (2010)

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Abstract

A novel capillary electrophoresis and amperometric detection method was achieved by adding an electroactive additive (3,4-dihydroxybenzylamine, 3,4-DHBA) to the running buffer, so that both electroactive and non-electroactive food preservatives were simultaneously determined. Under the selected optimum conditions, four electroactive preservatives (methylparaben, ethylparaben, propylparaben and butylparaben) and two non-electroactive preservatives (potassium sorbate and sodium lactate) were well separated and sensitively detected with detection limits (S/N=3) ranging from 1.06×10(-8) to 2.73×10(-6) g mL(-1). This method has been successfully employed for the determination of both electroactive and non-electroactive preservatives in several food commodities.Copyright © 2010 Elsevier B.V. All rights reserved.