Bi-metallic activation in homogeneous catalysis: palladium-catalysed carbonylation of tricarbonyl (chloroarene) chromium complexes to the corresponding aldehydes, …

R Mutin, C Lucas, J Thivolle-Cazat, V Dufaud…

Index: Mutin, Robert; Lucas, Christine; Thivolle-Cazat, Jean; Dufaud, Veronique; Dany, Fabienne; Basset, Jean Marie Journal of the Chemical Society, Chemical Communications, 1988 , # 13 p. 896 - 898

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Citation Number: 35

Abstract

The palladium-catalysed carbonylation of aryl bromides or iodides to give aromatic carboxylic acids,l esters,* amides ,3 aldehydes,4 a-0x0 amides,5 a-0x0 esters,6 and a-0x0 acids7 is well known. However, no reliable example of carbonylation of chlorobenzene has been reported; this would be of great industrial interest in view of the low cost of chloroaromatic compounds as compared with bromo or iodo analogues. The difficulty of carrying out the ...