The Journal of Organic Chemistry

A Study of the Regioselectivity of the Radical Addition of" RSAr" Derived from the Photolysis of tert-Homoallyl and tert-Alkyl 4-Nitrobenzenesulfenates to Substituted …

DJ Pasto, F Cottard

Index: Pasto, Daniel J.; Cottard, Francois Journal of Organic Chemistry, 1994 , vol. 59, # 16 p. 4642 - 4646

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Citation Number: 7

Abstract

The photolysis of 8a-c in the presence of llDMA has been carried out in freeze-degassed solutions of the reactants in benzene46 in sealed NMR tubes. The lH NMR spectra of the reaction mixtures taken after the complete disappearance of 8a-c indicated the clean formation of only the products shown in eq 4. The relative amounts of the products formed were determined by the direct integration of the 'Hnmr spectra of the reaction mixtures. ...