Applied Catalysis A: General

Palladium-1, 10-phenanthroline complex encaged in Y zeolite: An efficient and highly recyclable heterogeneous catalyst for aminocarbonylation

H Mei, J Hu, S Xiao, Y Lei, G Li

Index: Mei, Hui; Hu, Jianglin; Xiao, Se; Lei, Yizhu; Li, Guangxing Applied Catalysis A: General, 2014 , vol. 475, p. 40 - 47

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Citation Number: 15

Abstract

Abstract A promising route for catalytic synthesis of amides by aminocarbonylation of aryl iodides with amines is described using a palladium-1, 10-phenanthroline complex encaged in Y zeolite. Complete conversions for aryl iodides and good to excellent yields (71–97%) of various amides were obtained at low Pd loadings of 0.6 mol%. The turnover frequency (TOF) could be up to 139 h− 1. A satisfactory yield was obtained even after the catalyst was ...