Polyhedron

Iron (III) chloride–benzotriazole adducts with trigonal bipyramidal geometry: Spectroscopic, structural and catalytic studies

…, G Bilis, JC Plakatouras, CP Raptopoulou, V Psycharis…

Index: Anastasiadis, Nikolaos C.; Bilis, George; Plakatouras, John C.; Raptopoulou, Catherine P.; Psycharis, Vassilis; Beavers, Christine; Teat, Simon J.; Louloudi, Maria; Perlepes, Spyros P. Polyhedron, 2013 , vol. 64, p. 189 - 202

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Citation Number: 5

Abstract

Abstract The reactions of FeCl 3 with benzotriazole (btaH), 1-methylbenzotriazole (Mebta), 5, 6-dimethylbenzotriazole (5, 6Me 2 btaH) and 5-chlorobenzotriazole (5ClbtaH) were studied in non-polar solvents. The new solid complexes [FeCl 3 (btaH) 2](1),[FeCl 3 (Mebta) 2](2),[FeCl 3 (5, 6Me 2 btaH) 2](3) and [FeCl 3 (5ClbtaH) 2]· 2 (5ClbtaH)(4) have been isolated. The structures of the complexes have been determined by single-crystal, X-ray ...