Chemsuschem Chemistry And Sustainability, Energy & Materials 2015-08-10

Reduction of charge and discharge polarization by cobalt nanoparticles-embedded carbon nanofibers for Li-O2 batteries.

Yun-Jung Kim, Hongkyung Lee, Dong Jin Lee, Jung-Ki Park, Hee-Tak Kim

Index: ChemSusChem 8 , 2496-502, (2015)

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Abstract

The problem of high charge polarization is one of the most significant challenges in current nonaqueous Li-O2 batteries. The development of an electrode for the oxygen evolution reaction (OER) at reduced overpotential is thus essential. Here, we suggest a binder-free electrode based on Co nanoparticles embedded in carbon nanofibers (Co-CNFs), which simultaneously reduces the charge and discharge polarization and extends cycling stability. Co-CNF gives rise to a lower discharge polarization because of an enhanced oxygen reduction reaction activity compared to Co-free CNF. Although the embedment of Co does not enhance the OER activity, it significantly reduces charge overvoltage by forming easily decomposable amorphous Li2 O2 . A mechanism for the formation of amorphous Li2 O2 is suggested in terms of charge localization induced by the Co NPs. The findings suggest a new electrode design strategy of combining inexpensive metals and carbon materials for modulating the phase of the discharge product. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.