Synthesis, Structure, and C–C Cross??Coupling Activity of (Amine) bis (phenolato) iron (acac) Complexes

K Hasan, LN Dawe, CM Kozak

Index: Hasan, Kamrul; Dawe, Louise N.; Kozak, Christopher M. European Journal of Inorganic Chemistry, 2011 , # 29 p. 4610 - 4621

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Citation Number: 13

Abstract

Abstract A series of (amine) bis (phenolato) iron (III) acac complexes has been prepared and characterized. Reaction of Fe (acac) 3 with the diprotonated linear tetradentate proligand N, N′-bis (4, 6-di-tert-butyl-2-methylphenol)-N, N′-dimethyl-1, 2-diaminoethane, H 2 [L1], and tripodal tetradentate ligand precursors dimethylaminoethylamino-N, N-bis (2-methylene- 4, 6-di-tert-butylphenol), H 2 [L2], dimethylaminoethylamino-N, N-bis (2-methylene-4- ...