Chemical Communications 2013-02-28

Rapid one-pot propargylamine synthesis by plasmon mediated catalysis with gold nanoparticles on ZnO under ambient conditions.

María González-Béjar, Kate Peters, Geniece L Hallett-Tapley, Michel Grenier, Juan C Scaiano

Index: Chem. Commun. (Camb.) 49(17) , 1732-4, (2013)

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Abstract

Surface plasmon excitation of gold nanoparticles on ZnO in the presence of an aldehyde, an amine and phenylacetylene led to rapid and selective formation of propargylamines with good yields (50-95%) at room temperature. Plasmon mediated catalysis is the best available route for this ternary coupling.