Chemistry Letters

Photooxidation of some mesoionic and related systems

H Kato, K Tani, H Eurumisawa, Y Tamura

Index: Kato, Hiroshi; Tani, Kazue; Kurumisawa, Haruki; Tamura, Yoshiko Chemistry Letters, 1980 , p. 717 - 720

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Citation Number: 4

Abstract

Photooxidation of several mesoionic compounds gave ring cleavage products, some of which were apparently formed via the endoperoxides of the mesoionic rings. Photooxidation of a Δ 2-oxazolin-4-one and a Δ 2-thiazolin-4-one gave the corresponding 4, 4′-bisoxa-and bisthiazolinone in dichloromethane, whereas the former gave benzamide in dimethylformamide.

~4%

Detail

~3%

Detail

~13%

~1%

~0%

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~1%

~29%

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~69%

~19%

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