Preparation of 1, 3-diketones by the claisen reaction

JM Sprague, LJ Beckham, H Adkins

Index: Sprague; Beckham; Adkins Journal of the American Chemical Society, 1934 , vol. 56, p. 2665,2666

Full Text: HTML

Citation Number: 28

Abstract

Rather large quantities of a number of 1, 3-diketones were needed in this Laboratory for studies involving the relation of their structures to the mode of cleavage by water, alcohol and hydr0gen. l Our experience in the preparation of these diketones (see Table I) by the condensation of an ester with a simple ketone according to the Claisen reaction has, we believe, illuminated somewhat the preparational process.

12-Tungstophosphoric acid supported on nano silica from rice...

[Rafiee, Ezzat; Khodayari, Maryam; Shahebrahimi, Shabnam; Joshaghani, Mohammad Journal of Molecular Catalysis A: Chemical, 2011 , vol. 351, p. 204 - 209]

Ruthenium-catalyzed reductive alkylation of active methylene...

[Abe, Fujio; Hayashi, Teruyuki; Tanaka, Masato Chemistry Letters, 1990 , # 5 p. 765 - 768]

Selective. ALPHA.-Mono-and. ALPHA.,. ALPHA.-Dialkylations of...

[Yoshihara, Nobutoshi; Kitagawa, Teruhiro; Ihara, Ikuko; Hasegawa, Sadao; Hasegawa, Tadashi Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 4 p. 1185 - 1187]

A dual mechanistic pathway in the alkylation of pentane-2, 4...

[Marquet, J.; Moreno-Manas, M.; Pacheco, P.; Vallribera, A. Tetrahedron Letters, 1988 , vol. 29, # 12 p. 1465 - 1468]

Catalyst-Controlled C–C σ Bond Cleavages in Metal Halide-Cat...

[Nakano, Takeo; Endo, Kohei; Ukaji, Yutaka Organic Letters, 2014 , vol. 16, # 5 p. 1418 - 1421]