Journal of Organometallic Chemistry

Facile synthesis of substituted alkynes by nano-palladium catalyzed oxidative cross-coupling reaction of arylboronic acids with terminal alkynes

X Nie, S Liu, Y Zong, P Sun, J Bao

Index: Nie, Xiaopeng; Liu, Suli; Zong, Yan; Sun, Peipei; Bao, Jianchun Journal of Organometallic Chemistry, 2011 , vol. 696, # 8 p. 1570 - 1573

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Citation Number: 18

Abstract

The oxidative cross-coupling of terminal alkynes with arylboronic acids catalyzed by the porous palladium nanospheres was developed. In the presence of silver oxide, triphenylphosphine and cesium carbonate, the reaction provided the corresponding arylalkynes with good to excellent yields. There were also other obvious advantages such as broad applicability, high selectivity, simple experimental operation as well as the ...