Ethyl propiolate

Modify Date: 2024-01-02 12:29:09

Ethyl propiolate Structure
Ethyl propiolate structure
Common Name Ethyl propiolate
CAS Number 623-47-2 Molecular Weight 98.100
Density 1.0±0.1 g/cm3 Boiling Point 120.0±0.0 °C at 760 mmHg
Molecular Formula C5H6O2 Melting Point 9°C
MSDS Chinese USA Flash Point 23.3±0.0 °C
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning

 Names

Name ethyl propiolate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.0±0.1 g/cm3
Boiling Point 120.0±0.0 °C at 760 mmHg
Melting Point 9°C
Molecular Formula C5H6O2
Molecular Weight 98.100
Flash Point 23.3±0.0 °C
Exact Mass 98.036781
PSA 26.30000
LogP 1.42
Vapour Pressure 15.5±0.2 mmHg at 25°C
Index of Refraction 1.419
Storage condition 2-8°C
Water Solubility miscible

 Safety Information

Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning
Hazard Statements H226-H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi:Irritant;
Risk Phrases R10;R36/37/38
Safety Phrases S26-S36-S37/39-S16
RIDADR UN 3272 3/PG 3
WGK Germany 3
Packaging Group II
Hazard Class 3
HS Code 2916190090

 Synthetic Route

~61%

Ethyl propiolate Structure

Ethyl propiolate

CAS#:623-47-2

Literature: Jung,M-E.; Buszek,K.R. Journal of the American Chemical Society, 1988 , vol. 110, p. 3965

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Detail
Literature: American Cyanamid Company Patent: US6358980 B1, 2002 ; US 6358980 B1

~70%

Ethyl propiolate Structure

Ethyl propiolate

CAS#:623-47-2

Detail
Literature: American Cyanamid Company Patent: US6277885 B1, 2001 ;

~%

Ethyl propiolate Structure

Ethyl propiolate

CAS#:623-47-2

Literature: Angewandte Chemie - International Edition, , vol. 53, # 16 p. 4154 - 4158 Angew. Chem., , vol. 126, # 16 p. 4238 - 4242,5

~%

Detail
Literature: Helvetica Chimica Acta, , vol. 83, # 5 p. 1022 - 1048

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Ethyl propiolate Structure

Ethyl propiolate

CAS#:623-47-2

Literature: Tetrahedron Letters, , vol. 23, # 40 p. 4135 - 4138

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Ethyl propiolate Structure

Ethyl propiolate

CAS#:623-47-2

Literature: Zhurnal Obshchei Khimii, , vol. 20, p. 1729,1731;engl.Ausg.S.1787,1789

~%

Ethyl propiolate Structure

Ethyl propiolate

CAS#:623-47-2

Literature: Zhurnal Obshchei Khimii, , vol. 20, p. 1729,1731;engl.Ausg.S.1787,1789

 Customs

HS Code 2916190090
Summary 2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

 Articles4

More Articles
Influence of harvesting technique and maceration process on aroma and phenolic attributes of Sauvignon blanc wine.

Food Chem. 183 , 181-9, (2015)

Sauvignon blanc wines are characterised by their varietal aromas and low phenolic content. Mechanical harvesting has been shown to increase several varietal aromas. Likewise, maceration techniques hav...

Organocatalytic asymmetric direct alpha-alkynylation of cyclic beta-ketoesters.

J. Am. Chem. Soc. 129 , 441, (2007)

The first organocatalytic enantioselective direct alpha-alkynylation of beta-ketoesters and 3-acyl oxindoles is described. It is demonstrated that activated beta-halo-alkynes undergo nucleophilic acet...

Development of a gold-multifaceted catalysis approach to the synthesis of highly substituted pyrroles: mechanistic insights via Huisgen cycloaddition studies.

J. Org. Chem. 78(3) , 920-34, (2013)

A novel gold-catalyzed method for the regioselective synthesis of highly substituted pyrroles directly from oximes and alkynes was developed via independent optimization of two key steps of the proces...

 Synonyms

MFCD00009184
Ethyl 2-propynoate
ethyl prop-2-ynoate
2-Propynoic acid, ethyl ester
EINECS 210-795-8
Ethyl propiolate
Propiolic acid, ethyl ester
Ethylprop-2-inoat
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