Tetrahedron

HNO made-easy from photochemical cycloreversion of novel 3, 5-heterocyclic disubstituted 1, 2, 4-oxadiazole-4-oxides

…, D Dondi, B Mannucci, F Corana, P Quadrelli

Index: Memeo, Misal Giuseppe; Dondi, Daniele; Mannucci, Barbara; Corana, Federica; Quadrelli, Paolo Tetrahedron, 2013 , vol. 69, # 35 p. 7387 - 7394

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Citation Number: 4

Abstract

Abstract A variety of symmetric and asymmetric 3, 5-heterocyclic disubstituted 1, 2, 4- oxadiazole-4-oxides have been prepared through cycloaddition of aromatic and heteroaromatic nitrile oxides to heteroaromatic amidoximes. A library of novel, fully characterized, 1, 2, 4-oxadiazole-4-oxides has been obtained as valuable precursors, upon photochemical activation, of new nitrosocarbonyl intermediates. The photochemical ...