Bulletin of the Chemical Society of Japan

Ring Cleavage in Liquid Sulfur Dioxide. I. Cleavage of Cyclic 1, 2-Diketone Monoximes

D Murakami, N Tokura

Index: Murakami; Tokura Bulletin of the Chemical Society of Japan, 1958 , vol. 31, p. 1044,1047

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Citation Number: 7

Abstract

1044 Daisaburo Murakami and Niichiro Tokura [Vol. 31, No. 9 Ring Cleavage in Liquid Sulfur Dioxide. I. Cleavage of Cyclic 1,2-Diketone Monoximes By Daisaburo Murakami and Niichiro Tokura (Received July 7, 1958) When a 1,2-diketone 1-monoxime is treated under the conditions of the Beck- mann rearrangement, it is cleaved into two fragments, a cyano compound and a carboxylic acid1'25. This reaction, desig- nated as the Beckmann rearrangement of the ...