The Journal of Organic Chemistry

Enantiotopically selective oxidation of. alpha.,. omega.-diols with enzyme systems of microorganisms

H Ohta, H Tetsukawa, N Noto

Index: Ohta, Hiromichi; Tetsukawa, Hatsuki; Noto, Naoko Journal of Organic Chemistry, 1982 , vol. 47, # 12 p. 2400 - 2404

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Citation Number: 57

Abstract

Results Gluconobacter and Acetobacter have been well-known to oxidize a variety of primary and secondary alcohols.'Thus, various strains of Gluconobacter were examined by using 2-methylpropane-1, 3-diol (la) as the simplest substrate that has a, w-diol functions with a prochiral center.

609-08-5

Ethyl methylmalonate

~88%

~53%

~95%

~55%

~8%

~78%

~1%

~31%

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