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115-96-8

115-96-8 structure
115-96-8 structure
Name tris(2-chloroethyl) phosphate
Synonyms Celluflex
MFCD00000967
2-Chloroethanol phosphate (3:1)
Phosphoric Acid Tris(2-chloroethyl) Ester
Tri(β-chloroethyl) phosphate
fyrolcef
Tris(2-chloroethyl) phosphate
Phosphoric acid, tris(2-chloroethyl) ester
Tris(β-chloroethyl) phosphate
Niax 3CF
EINECS 204-118-5
Genomoll P
G2OPO&O2GO2G
3CF
TCBP
TCEP
Fyrol CF
Tris(2-chloroethyl) orthophosphate
Density 1.4±0.1 g/cm3
Boiling Point 347.4±0.0 °C at 760 mmHg
Melting Point -51 °C
Molecular Formula C6H12Cl3O4P
Molecular Weight 285.490
Flash Point 232.2±0.0 °C
Exact Mass 283.953888
PSA 54.57000
LogP 0.48
Vapour Pressure 0.0±0.7 mmHg at 25°C
Index of Refraction 1.463
Stability Stable. Incompatible with strong bases, strong oxidizing agents.
Water Solubility 7 g/L (20 ºC)

CHEMICAL IDENTIFICATION

RTECS NUMBER :
KK2450000
CAS REGISTRY NUMBER :
115-96-8
BEILSTEIN REFERENCE NO. :
1710938
LAST UPDATED :
199806
DATA ITEMS CITED :
26
MOLECULAR FORMULA :
C6-H12-Cl3-O4-P
MOLECULAR WEIGHT :
285.50
WISWESSER LINE NOTATION :
G2OPO&O2GO2G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1230 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1866 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
250 mg/kg
TOXIC EFFECTS :
Behavioral - altered sleep time (including change in righting reflex) Behavioral - convulsions or effect on seizure threshold
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
2 gm/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - lacrimation Behavioral - somnolence (general depressed activity) Gastrointestinal - other changes
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2100 mg/kg/16D-I
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - changes in lung weight Kidney, Ureter, Bladder - changes in bladder weight Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
28 gm/kg/16W-I
TOXIC EFFECTS :
Brain and Coverings - other degenerative changes Liver - changes in liver weight Kidney, Ureter, Bladder - changes in bladder weight
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
56 gm/kg/16W-I
TOXIC EFFECTS :
Liver - changes in liver weight Kidney, Ureter, Bladder - other changes Kidney, Ureter, Bladder - changes in bladder weight
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
56 gm/kg/16W-I
TOXIC EFFECTS :
Liver - changes in liver weight Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis) Kidney, Ureter, Bladder - changes in bladder weight
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
45760 mg/kg/2Y-C
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Kidney, Ureter, Bladder - Kidney tumors
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
182 gm/kg/2Y-C
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Liver - tumors Kidney, Ureter, Bladder - Kidney tumors
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
1800 mg/kg
SEX/DURATION :
female 7-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Newborn - behavioral
TYPE OF TEST :
Micronucleus test

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Rodent - hamster Lung
DOSE/DURATION :
700 mg/L
REFERENCE :
EJCODS European Journal of Cancer and Clinical Oncology. (Pergamon Press, c/o Elsevier Science, 660 White Plains Rd., Tarrytown, NY 10591) V.17(7)- 25, 1981-89. For publisher information, see EJCAEL Volume(issue)/page/year: 18,1337,1982 *** REVIEWS *** IARC Cancer Review:Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 48,109,1990 IARC Cancer Review:Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 48,109,1990 TOXICOLOGY REVIEW CTOXAO Clinical Toxicology. (New York, NY) V.1-18, 1968-81. For publisher information, see JTCTDW. Volume(issue)/page/year: 17,101,1980 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M0756 No. of Facilities: 95 (estimated) No. of Industries: 5 No. of Occupations: 9 No. of Employees: 762 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M0756 No. of Facilities: 278 (estimated) No. of Industries: 6 No. of Occupations: 5 No. of Employees: 5073 (estimated) No. of Female Employees: 578 (estimated)
Symbol GHS07 GHS08 GHS09
GHS07, GHS08, GHS09
Signal Word Danger
Hazard Statements H302-H351-H360F-H411
Precautionary Statements P201-P273-P281-P308 + P313
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xn:Harmful
Risk Phrases R22;R40;R51/53
Safety Phrases S36/37-S61
RIDADR UN 2810 6.1/PG 3
WGK Germany 3
RTECS KK2450000
HS Code 2919900090
75-21-8 structure

75-21-8

~99%

115-96-8 structure

115-96-8

Literature: Zhi, Hui Zhen; Shi, Hong Li; Hu, Yun; Xia, Ke Dan; Zhang, Peng; Yang, Jin Fei Chinese Chemical Letters, 2012 , vol. 23, # 11 p. 1217 - 1220,4
107-07-3 structure

107-07-3

~89%

115-96-8 structure

115-96-8

Literature: Ilia, Gheorghe; Caprita, Adrian; Dehelean, Gheorghe Revue Roumaine de Chimie, 1995 , vol. 40, # 4 p. 391 - 399
140-08-9 structure

140-08-9

~%

115-96-8 structure

115-96-8

Literature: Chemische Berichte, , vol. 90, p. 801,807
54509-73-8 structure

54509-73-8

~%

115-96-8 structure

115-96-8

Literature: Zhurnal Obshchei Khimii, , vol. 24, p. 1631,1634;engl.Ausg.S.1613
107-07-3 structure

107-07-3

10025-87-3 structure

10025-87-3

~%

115-96-8 structure

115-96-8

Literature: Journal of the Chemical Society, , p. 298
60-29-7 structure

60-29-7

140-08-9 structure

140-08-9

~%

115-96-8 structure

115-96-8

Literature: Chemische Berichte, , vol. 90, p. 801,807
HS Code 2919900090
Summary 2919900090 other phosphoric esters and their salts, including lactophosphates; their halogenated, sulphonated, nitrated or nitrosated derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

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