356-32-1

356-32-1 structure
356-32-1 structure
  • Name: methyl 2,2,3,3,4,4-hexafluorobutanoate
  • Chemical Name: methyl 2,2,3,3,4,4-hexafluorobutanoate
  • CAS Number: 356-32-1
  • Molecular Formula: C5H4F6O2
  • Molecular Weight: 210.07400
  • Create Date: 2018-12-24 17:36:08
  • Modify Date: 2024-01-09 13:29:57

Name methyl 2,2,3,3,4,4-hexafluorobutanoate
Synonyms 1-Monohydrogenperfluor-n-buttersaeuremethylester
Methyl 2,2,3,3,4,4-hexafluorobutyrate
Density 1.422g/cm3
Boiling Point 99.8ºC at 760mmHg
Molecular Formula C5H4F6O2
Molecular Weight 210.07400
Flash Point 14.7ºC
Exact Mass 210.01200
PSA 26.30000
LogP 1.69510
Index of Refraction 1.302
Name: Methyl 2,2,3,3,4,4-hexafluorobutanoate, 97% Material Safety Data Sheet
Synonym:
CAS: 356-32-1
Section 1 - Chemical Product MSDS Name: Methyl 2,2,3,3,4,4-hexafluorobutanoate, 97% Material Safety Data Sheet
Synonym:

SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
356-32-1 Methyl 2,2,3,3,4,4-hexafluorobutanoate 97% unlisted
+++++
Hazard Symbols: XI
SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin. Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.
SECTION 4 - FIRST AID MEASURES
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
SECTION 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.
SECTION 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 356-32-1: Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 113 - 115 deg C @760mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C5H4F6O2
Molecular Weight: 210
SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acrid smoke and fumes, fluorine, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported
SECTION 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 356-32-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Methyl 2,2,3,3,4,4-hexafluorobutanoate - Not listed by ACGIH, IARC, or NTP.
SECTION 12 - ECOLOGICAL INFORMATION
SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations.
SECTION 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available.
SECTION 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 356-32-1: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 356-32-1 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 356-32-1 is not listed on the TSCA inventory. It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION
MSDS Creation Date: 3/21/2003 Revision #0 Date: Original. The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages.

SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S37/39
HS Code 2915900090

~%

Detail
Literature: Mazin; Mysov; Sterlin; Grinberg Journal of Fluorine Chemistry, 1998 , vol. 88, # 1 p. 29 - 35

~%

356-32-1 structure

356-32-1

Literature: Berenblit,V.V. et al. Journal of Organic Chemistry USSR (English Translation), 1974 , vol. 10, p. 2525 - 2528 Zhurnal Organicheskoi Khimii, 1974 , vol. 10, p. 2507 - 2510

~%

356-32-1 structure

356-32-1

Literature: Yuminov Russian Journal of Organic Chemistry, 1998 , vol. 34, # 12 p. 1715 - 1720

~%

356-32-1 structure

356-32-1

Literature: Yuminov Russian Journal of Organic Chemistry, 1998 , vol. 34, # 12 p. 1715 - 1720
HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%