Name | 2-amino-5-phenylfuran-3-carbonitrile |
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Synonyms |
2-amino-5-phenyl-3-cyanofuran
MFCD00463472 2-amino-5-phenyl-3-furonitrile 2-Amino-5-phenyl-furan-3-carbonitrile 2-amino-3-cyano-5-phenylfuran F0777-1641 2-amino-5-phenyl-3-furancarbonitrile |
Density | 1.26g/cm3 |
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Boiling Point | 378.8ºC at 760mmHg |
Melting Point | 196ºC |
Molecular Formula | C11H8N2O |
Molecular Weight | 184.19400 |
Flash Point | 182.9ºC |
Exact Mass | 184.06400 |
PSA | 62.95000 |
LogP | 2.98168 |
Vapour Pressure | 6.12E-06mmHg at 25°C |
Index of Refraction | 1.633 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/21/22 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. May cause respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 14742-32-6: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 196 - 198 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C11H8N2O Molecular Weight: 184 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 14742-32-6 unlisted. LD50/LC50: Not available. Carcinogenicity: 2-Amino-5-phenyl-3-furonitrile - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: NITRILES, SOLID, TOXIC, N.O.S.* Hazard Class: 6.1 UN Number: 3276 Packing Group: III IMO Shipping Name: NITRILES, TOXIC, N.O.S. Hazard Class: 6.1 UN Number: 3276 Packing Group: III RID/ADR Shipping Name: NITRILES, TOXIC, N.O.S. Hazard Class: 6.1 UN Number: 3276 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. Safety Phrases: S 36/37 Wear suitable protective clothing and gloves. WGK (Water Danger/Protection) CAS# 14742-32-6: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 14742-32-6 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 14742-32-6 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | Xi: Irritant; |
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Risk Phrases | 22-36 |
Safety Phrases | 26 |
HS Code | 2932190090 |
~80% 14742-32-6 |
Literature: Bakavoli, Mehdi; Rahimizadeh, Mohammad; Gordi, Zinat Journal of Chemical Research, 2008 , # 10 p. 564 - 565 |
~70% 14742-32-6 |
Literature: Abdelhamid, Abdou O.; Negm, Abdalla M.; Abbas, Ikhlass M. Journal fuer Praktische Chemie (Leipzig), 1989 , vol. 331, # 1 p. 31 - 36 |
~14% 14742-32-6 |
Literature: Foley, Louise H. Tetrahedron Letters, 1994 , vol. 35, # 33 p. 5989 - 5992 |
~89% 14742-32-6 |
Literature: Nasakin; Sheverdov; Moiseeva; Ershov; Chernushkin; Tafeenko Russian Journal of General Chemistry, 1999 , vol. 69, # 2 p. 291 - 300 |
~% 14742-32-6 |
Literature: Maeda, Yutaka; Nakano, Masato; Sato, Hideyuki; Miyazaki, Yasushi; Schweiker, Stephanie L.; Smith, Jeffery L.; Truesdale, Anne T. Bioorganic and Medicinal Chemistry Letters, 2004 , vol. 14, # 15 p. 3907 - 3911 |
Precursor 3 | |
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DownStream 2 | |
HS Code | 2932190090 |
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Summary | 2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0% |