Name | ethylmagnesium chloride |
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Synonyms |
EthylMagnesiuM Chloride
inTetrahydrofuran,ca.2mol/l) chloroethyl-magnesiu EINECS 219-206-9 chloroethylmagnesium Ethylmagnes Ethylchloromagnesium Magnesium,chloroethyl ethyl magnesium chloride MFCD00000472 Ethylmagnesiumchloride,2Minether Chlorethylmagnesium |
Density | 1.00 g/mL at 20 °C |
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Molecular Formula | C2H5ClMg |
Molecular Weight | 88.81910 |
Flash Point | 1 °F |
Exact Mass | 87.99300 |
LogP | 1.66340 |
Storage condition | water-free area |
Version 1.4
Regulation (EC) No 1907/2006 1 - Product and Company Information Product NameETHYLMAGNESIUM CHLORIDE SOLUTION, APPROX. 2.8 M IN TETRAHYDROFURAN 2 - Hazards Identification SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT Highly flammable. Reacts violently with water, liberating extremely flammable gases. Causes burns. 3 - Composition/Information on Ingredients Product NameCAS #EC noAnnex I Index Number ETHYLMAGNESIUM CHLORIDE SOLUTION, NoneNoneNone ~2.8 M IN TETRAHYDROFURAN Ingredient NamePercentCAS #EC noAnnex I Index Number ETHYLMAGNESIUM CHLORIDE >= 202386-64-3219-206-9 None <= 25 TETRAHYDROFURAN>= 75109-99-9 203-726-8 603-025-00-0 (Inhibitor free)<= 80 Symbols: F-Xi R-Phrases: 11-19-36/37 Highly flammable. May form explosive peroxides. Irritating to eyes and respiratory system. FormulaC2H5ClMg Molecular Weight 88,8300 AMU 4 - First Aid Measures AFTER INHALATION If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. AFTER EYE CONTACT FLUKAwww.molbase.com Assure adequate flushing of the eyes by separating the eyelids with fingers. AFTER INGESTION If swallowed, wash out mouth with water provided person is conscious. Call a physician. 5 - Fire Fighting Measures CONDITIONS OF FLAMMABILITY Reacts with water to liberate flammable and/or explosive gas. EXTINGUISHING MEDIA Suitable: Dry chemical powder. Unsuitable: Do not use water. SPECIAL RISKS Specific Hazard(s): Vapor may travel considerable distance to source of ignition and flash back. Emits toxic fumes under fire conditions. Explosion Hazards: Vapor may travel considerable distance to source of ignition and flash back. Container explosion may occur under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. 6 - Accidental Release Measures PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL Evacuate area. Shut off all sources of ignition. PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP Cover with dry-lime, sand, or soda ash. Place in covered containers using non-sparking tools and transport outdoors. Ventilate area and wash spill site after material pickup is complete. 7 - Handling and Storage HANDLING Directions for Safe Handling: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE Conditions of Storage: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. Incompatible Materials: Do not allow contact with water 8 - Exposure Controls / Personal Protection ENGINEERING CONTROLS Safety shower and eye bath. Use only in a chemical fume hood. FLUKAwww.molbase.com GENERAL HYGIENE MEASURES Wash thoroughly after handling. PERSONAL PROTECTIVE EQUIPMENT Special Protective Measures: Wear appropriate government approved respirator, chemical-resistant gloves, safety goggles, other protective clothing. Faceshield (8-inch minimum). 9 - Physical and Chemical Properties AppearancePhysical State: Liquid Color: Dark - brown PropertyValueAt Temperature or Pressure pH N/A BP/BP RangeN/A MP/MP RangeN/A Flash Point- 17,000 °C.Method: closed cup FlammabilityN/A Autoignition TempN/A Oxidizing Properties N/A Explosive Properties N/A Explosion LimitsN/A Vapor PressureN/A SG/Density0,9780 g/cm3 Partition Coefficient N/A ViscosityN/A Vapor DensityN/A Saturated Vapor Conc. N/A Evaporation RateN/A Bulk DensityN/A Decomposition Temp.N/A Solvent ContentN/A Water ContentN/A Surface TensionN/A ConductivityN/A Miscellaneous DataN/A SolubilityN/A 10 - Stability and Reactivity STABILITY Reactions to Avoid: Reacts violently with: Materials to Avoid: Water, Acids, Alcohols. HAZARDOUS DECOMPOSITION PRODUCTS Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide, Hydrogen chloride gas. 11 - Toxicological Information SIGNS AND SYMPTOMS OF EXPOSURE Coughing, chest pains, difficulty in breathing. Nausea, dizziness, and headache. Unconsciousness. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, FLUKAwww.molbase.com shortness of breath, headache, nausea, and vomiting. Narcotic effect. Exposure can cause: Can cause CNS depression. ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. TARGET ORGAN INFORMATION Central nervous system. Liver. Kidneys. 12 - Ecological Information No data available. 13 - Disposal Considerations SUBSTANCE DISPOSAL Under an inert atmosphere, cautiously add the material to dry butanol in an appropriate solvent. The chemical reaction may be vigorous and/or exothermic. Provisions must be made for the venting of large volumes of highly flammable hydrogen and/or hydrocarbon gases. Neutralize the solution with aqueous acid. Filter off any solid residues for disposal as hazardous waste. Burn the liquid portion in a chemical incinerator equipped with an afterburner and scrubber. Observe all federal, state, and local environmental regulations. 14 - Transport Information RID/ADR UN#: 3399 Class: 4.3 PG: I Subrisk: 3 Proper Shipping Name: Organometallic substance, liquid, water-reactive, flammable IMDG UN#: 3399 Class: 4.3 PG: I Subrisk: 3 Proper Shipping Name: Organometallic substance, liquid, water-reactive, flammable Marine Pollutant: No Severe Marine Pollutant: No Technical Name: Required IATA UN#: 3399 Class: 4.3 PG: I Subrisk: 3 Proper Shipping Name: Organometallic substance, liquid, water-reactive, flammable Inhalation Packing Group I: No Technical Name: Required 15 - Regulatory Information FLUKAwww.molbase.com CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES INDICATION OF DANGER: F-C Highly Flammable. Corrosive. R-PHRASES: 11-14/15-34 Highly flammable. Reacts violently with water, liberating extremely flammable gases. Causes burns. S-PHRASES: 7/8-26-30-36/37/39-43-45 Keep container tightly closed and dry. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Never add water to this product. Wear suitable protective clothing, gloves, and eye/face protection. In case of fire, use special powder for metal fire. Never use water. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Caution: Substance not yet fully tested (EU). COUNTRY SPECIFIC INFORMATION Germany WGK: 1 Self-Classification 16 - Other Information WARRANTY The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Inc., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. Copyright 2010 Co. License granted to make unlimitedpaper copies for internal use only. DISCLAIMER For R&D use only. Not for drug, household or other uses. FLUKAwww.molbase.com SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | F:Flammable;C:Corrosive; |
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Risk Phrases | R11;R14/15;R19;R22;R34 |
Safety Phrases | S26-S30-S36/37/39-S43-S45-S7/8-S33-S16-S6A-S43A-S24/25 |
RIDADR | UN 3399 4.3/PG 1 |
WGK Germany | 1 |
HS Code | 2931900090 |
Precursor 2 | |
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DownStream 10 | |
HS Code | 2931900090 |
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Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |