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12136-78-6

12136-78-6 structure
12136-78-6 structure

Name molybdenum silicide
Synonyms EINECS 235-231-8
MFCD00151535
bis(λ<sup>2</sup>-silanylidene)molybdenum
Molybdenum disiticide
Molybdenum silicide
Density 6.31
Melting Point 1930ºC
Molecular Formula MoSi2
Molecular Weight 152.13100
Exact Mass 153.85900
Water Solubility Insoluble in acids and aqua regia, however, it is soluble in HF and HNO{3}Soluble in nitric acid and hydrofluoric acid. Insoluble in water most acids.

Section 1: Product Identification
Chemical Name:Molybdenum silicide (99+%-Mo)
CAS Registry Number:12136-78-6
Formula:MoSi2
EINECS Number:235-231-8
Chemical Family:metal silicide
Synonym:Molybdenum disilicide

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound12136-78-6100%10mg/m3( as Mo)15mg/m3 (as Mo)

Section 3: Hazards Identification
Emergency Overview:May be irritating to skin and eyes and respiratory tract.
Primary Routes of Exposure:Ingestion, inhalation
Eye Contact:May be a mild to severe irritant to the eyes.
Skin Contact:May cause slight to mild irritation of the skin.
Inhalation:Do not breath dust. Inhalation of powder may lead to irritation of the respiratory tract.
Ingestion:No information is available on the physiological effects of ingestion.
Acute Health Affects:May be irritating to skin, eyes, mucous membranes and respiratory tract. Do not breath dust.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in
Inhalation:
breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, dry powder or foam.
If involved in a fire, fire fighters should be equipped with NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion andNo hazardous combustion or decomposition products.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Handling and Storage:No special precautions needed in handling and storage..

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:black powder
Molecular Weight:152.13
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:6.31
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable.
Hazardous Polymerization:No hazardous polymerization.
Conditions to Avoid:none
Incompatibility:oxidizing agents
Decomposition Products:none

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302-H312-H332
Precautionary Statements P280
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xn: Harmful;
Risk Phrases R20/21/22
Safety Phrases 36
RIDADR NONH for all modes of transport
WGK Germany 3