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1702-17-6

1702-17-6 structure
1702-17-6 structure
Name clopyralid
Synonyms 3,6-DCP
benzalox
shield
Picolinic acid, 3,6-dichloro-
format
Clopyralid
2-Pyridinecarboxylic acid, 3,6-dichloro-
reclaim
3,6-Dichloropicolinic acid
3,6-Dichloro-pyridine-2-carboxylic acid
EINECS 216-935-4
cirtoxin
MFCD00078655
campaign
T6NJ BVQ CG FG
cyronal
3,6-Dichloro-2-pyridinecarboxylic acid
3,6-Dichloropyridine-2-carboxylic acid
LONCID
lontrel
Density 1.6±0.1 g/cm3
Boiling Point 323.7±37.0 °C at 760 mmHg
Melting Point 151-152°C
Molecular Formula C6H3Cl2NO2
Molecular Weight 191.999
Flash Point 149.6±26.5 °C
Exact Mass 190.954086
PSA 50.19000
LogP 1.30
Vapour Pressure 0.0±0.7 mmHg at 25°C
Index of Refraction 1.606
Storage condition 0-6°C
Water Solubility 1.0 g/L

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TJ7550700
CHEMICAL NAME :
Picolinic acid, 3,6-dichloro-
CAS REGISTRY NUMBER :
1702-17-6
BEILSTEIN REFERENCE NO. :
0473755
LAST UPDATED :
199710
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C6-H3-Cl2-N-O2
MOLECULAR WEIGHT :
192.00
WISWESSER LINE NOTATION :
T6NJ BVQ CG FG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
4300 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A433,1985
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
900 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 31,387,1977
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 31,387,1977
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 31,387,1977
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - duck
DOSE/DURATION :
1465 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,182,1991 ** REPRODUCTIVE DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
150 mg/kg
SEX/DURATION :
female 6-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 4,91,1984
Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H318
Precautionary Statements P280-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi:Irritant
Risk Phrases R41;R51/53
Safety Phrases S26-S30-S61-S39
RIDADR UN 3077
RTECS TJ7550700
Packaging Group III
Hazard Class 9
HS Code 2933399028
1702-18-7 structure

1702-18-7

~85%

1702-17-6 structure

1702-17-6

Literature: Kureha Kagaku Kogyo K.K. Patent: US6610853 B1, 2003 ;
32889-74-0 structure

32889-74-0

~%

1702-17-6 structure

1702-17-6

Literature: US4087431 A1, ;
16110-09-1 structure

16110-09-1

124-38-9 structure

124-38-9

~57%

1702-17-6 structure

1702-17-6

Literature: Marzi, Elena; Bigi, Anna; Schlosser, Manfred European Journal of Organic Chemistry, 2001 , # 7 p. 1371 - 1376
10469-09-7 structure

10469-09-7

~%

1702-17-6 structure

1702-17-6

Literature: Electrochimica Acta, , vol. 55, # 9 p. 3171 - 3174
HS Code 2933399028
Summary 2933399028 2-((3,5,6-trichloropyridin-2-yl)oxy)acetic acid。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:20.0%
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