6780-13-8

PHYSICAL HAZARDS
Category 3
Flammable liquids
HEALTH HAZARDS
Category 4
Acute toxicity (Oral)
Acute toxicity (Dermal)Category 3
Category 1B
Skin corrosion/irritation
Serious eye damage/eye irritationCategory 1
Category 1
Respiratory sensitization
Skin sensitizationCategory 1
Blood system, Respiratory system, Kidney
Specific target organ toxicity
- Single exposure [Category 1]
Liver, Visual system, Kidney
Specific target organ toxicity
- Repeated exposure [Category 2]
ENVIRONMENTAL HAZARDS
Acute aquatic hazardCategory 2
GHS label elements, including precautionary statements
Pictograms or hazard symbols
Danger
Signal word
Hazard statementsFlammable liquid and vapour
Harmful if swallowed
Toxic in contact with skin
Causes severe skin burns and eye damage
May cause allergy or asthma symptoms or breathing
difficulties if inhaled
May cause an allergic skin reaction
Causes damage to organs : Blood system Respiratory
system Kidney
May cause damage to organs through prolonged or
repeated exposure : Liver Visual system Kidney
Toxic to aquatic life
Precautionary statements:
Ethylenediamine Monohydrate

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Section2. HAZARDS IDENTIFICATION
[Prevention]Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Keep container tightly closed.
Use explosion-proof electrical/ventilating/lighting equipment. Take precautionary
measures against ignition by the static discharge and the spark.
Do not breathe dust/fume/gas/mist/vapours/spray.
Avoid release to the environment.
Do not eat, drink or smoke when using this product.
Contaminated work clothing should not be allowed out of the workplace.
Wash hands thoroughly after handling.
In case of inadequate ventilation wear respiratory protection.
Wear protective gloves and eye/face protection.
[Response]IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse
skin with water/shower.
If skin irritation or rash occurs: Get medical advice/attention.
Remove/Take off immediately all contaminated clothing.
Wash contaminated clothing before reuse.
Immediately call a POISON CENTER or doctor/physician.
Store in a well-ventilated place. Keep cool.
[Storage]
Store locked up.
Dispose of contents/container through a waste management company authorized by
[Disposal]
the local government.

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Section3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/mixture:Substance
Components:Ethylenediamine Monohydrate
Percent:>98.0%(T)
6780-13-8
CAS Number:
Chemical Formula:C2H8N2·H2O

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Section4. FIRST AID MEASURES
Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Immediately call a POISON CENTER or doctor/physician.
Skin contact:Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
soap and water. Immediately call a POISON CENTER or doctor/physician.
Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.Immediately call a POISON CENTER or
doctor/physician.
Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT
Ingestion:
induce vomiting.
Most importantBurning sensation, Cough, Shortness of breath, Sore throat, Wheezing, Abdominal
symptoms/effects, acute pain, Collapse, Redness, Burn, Pain, Blurred Vision
and delayed:
Protection of first-aiders: A rescuer should wear personal protective equipment, such as rubber gloves and air-
tight goggles.
Indication of immediate Medical ovservation is indicated.
medical attantion and
special treatment needed, if
necessary:
Ethylenediamine Monohydrate

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Section5. FIRE-FIGHTING MEASURES
Suitable extinguishingDry chemical, foam, water in large amounts, carbon dioxide.
media:
Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
from the chemical:generate poisonous fume.
Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
method according to the surrounding situation is used. Uninvolved persons should
evacuate to a safe place. In case of fire in the surroundings: Keep containers cool by
spraying with water. Eliminate all ignition sources if safe to do so.
Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment.
equipment for firefighters:

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Section6. ACCIDENTAL RELEASE MEASURES
Use extra personal protective equipment (self-contained breathing apparatus). Keep
Personal precautions,
protective equipment and people away from and upwind of spill/leak. Ensure adequate ventilation. Entry to non-
emergency procedures: involved personnel should be controlled around the leakage area by roping off, etc.
Environmental precautions: Prevent product from entering drains.
Methods and materials for Absorb spilled material in dry sand or inert absorbent before recovering it into an
containment and cleaning airtight container. In case of large amount of spillage, contain a spill by bunding.
up: Adhered or collected material should be promptly disposed of, in accordance with
appropriate laws and regulations.
Prevention of secondary Remove all sources of ignition. Fire-extinguishing devices should be prepared in
hazards:case of a fire. Use spark-proof tools and explosion-proof equipment.

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Section7. HANDLING AND STORAGE
Precautions for safe handling
Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment.
Prevent generation of vapour or mist. Keep away from heat/sparks/open flame/hot
surfaces. -No smoking. Take measures to prevent the build up of electrostatic
charge. Use explosion-proof equipment. Wash hands and face thoroughly after
handling.
Use a closed system if possible. Use a ventilation, local exhaust if vapour or aerosol
will be generated.
Advice on safe handling: Avoid contact with skin, eyes and clothing.
Conditions for safe storage, including any
incompatibilities
Keep container tightly closed. Store in a cool, dark and well-ventilated place.
Storage conditions:
Store under inert gas.
Store locked up.
Store away from incompatible materials such as oxidizing agents.
Air-sensitive
Packaging material:Comply with laws.

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Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls:Install a closed system or local exhaust. Also install safety shower and eye bath.
Personal protective equipment
Respiratory protection: Half or full facepiece respirator, self-contained breathing apparatus(SCBA), supplied
air respirator, etc. Use respirators approved under appropriate government standards
and follow local and national regulations.
Hand protection:Impervious gloves.
Eye protection:Safety goggles. A face-shield, if the situation requires.
Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires.

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Section9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state (20°C):Liquid
Form:Clear
Colour:Colorless - Very pale yellow
Odour:Ammoniacal
Ethylenediamine Monohydrate

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Section9. PHYSICAL AND CHEMICAL PROPERTIES
pH: 11.9/25°C (25% H2O soln.)
Melting point/freezing point:10°C
Boiling point/range:118°C
Flash point:No data available
Flammability or explosive
limits:
Lower:No data available
Upper:No data available
Relative density:0.96
Solubility(ies):
[Water]No data available
[Other solvents]No data available
Log Pow:-1.2

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Section10. STABILITY AND REACTIVITY
Chemical stability:Stable under proper conditions.
Possibility of hazardous No special reactivity has been reported.
reactions:
Spark, Open flame, Static discharge
Conditions to avoid:
Incompatible materials: Oxidizing agents, Acids, Metals, Halogens
Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx)
products:

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Section11. TOXICOLOGICAL INFORMATION
Acute Toxicity:No data available
Skin corrosion/irritation: No data available
Serious eyeNo data available
damage/irritation:
Germ cell mutagenicity: No data available
Carcinogenicity:
IARC =No data available
NTP =No data available
Reproductive toxicity:No data available

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Section12. ECOLOGICAL INFORMATION
Ecotoxicity:
Fish:No data available
No data available
Crustacea:
Algae:No data available
Persistence / degradability: No data available
Bioaccumulative<1
potential(BCF):
Mobility in soil
Log Pow:-1.2
Soil adsorption (Koc):4766
1.8 x 10-4
Henry's Law
constant(PaM3/mol):

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Section13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical
incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when
disposing of the substance.

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Section14. TRANSPORT INFORMATION
Hazards Class:8: Corrosive.
Subsidiary risk:3: Flammable liquid.
Ethylenediamine Monohydrate

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Section14. TRANSPORT INFORMATION
UN-No:1604
Proper shipping name:Ethylenediamine
Packing group:II

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Section15. REGULATORY INFORMATION
Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
loading and unloading were prescribed.

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SECTION 16 - ADDITIONAL INFORMATION
N/A