1908469-38-4
1908469-38-4 structure
- Name: SLAP N-Bn Pip Reagent
- Chemical Name: SLAP N-Bn Pip Reagent
- CAS Number: 1908469-38-4
- Molecular Formula: C13H24N2Si
- Molecular Weight: 236.44
- Create Date: 2023-01-21 15:38:03
- Modify Date: 2024-04-06 16:23:21
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Description Silicon amine protocol (SLAP) reagents, in conjunction with aldehydes and ketones, formN-unprotected piperazines via photocatalytic cross-coupling with Ir[(ppy)2dtbbpy]PF6(747769). Heteroaromatic, aromatic, and aliphatic aldehydes are well tolerated, as are structurally and stereochemically complex SLAP reagents. This product was introduced in collaboration with theBode Research Groupand provides a tin-free alternative toSnAP(tin amine protocol) reagents for piperazine synthesis.
| Name | SLAP N-Bn Pip Reagent |
|---|---|
| Synonyms | N1-Benzyl-N1-((trimethylsilyl)methyl)ethane-1,2-diamine |
| Density | 0.9366g/mL |
|---|---|
| Boiling Point | 265.4±20.0 °C at 760 mmHg |
| Molecular Formula | C13H24N2Si |
| Molecular Weight | 236.44 |
| Flash Point | 114.3±21.8 °C |
| Exact Mass | 236.170868 |
| LogP | 2.65 |
| Vapour Pressure | 0.0±0.5 mmHg at 25°C |
| Index of Refraction | 1.508 |