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95-49-8

95-49-8 structure
95-49-8 structure
Name 2-Chlorotoluene
Synonyms 2-Methylphenyl chloride
2-Methylchlorobenzene
O-Chlorotoluene Standd
2-Chlorotoluene, ML
O-Chlorotoluene, standd for ,>=
EINECS 202-424-3
2-Chloro-1-methylbenzene,o-tolylchloride
mono-chlorotoluene
2-CHLOROTOLUOL
2-CHLOROTOLUENE, 1000MG, NEAT
2-CHLORO-1-METHYLBENZENE
1-Methyl-2-chlorobenzene
1-CHLORO-2-METHYLBENZENE
Toluene, o-chloro
O-Methyl-capsaicin
Benzene,1-chloro-2-methyl
2-ChlorotolueneSolution,1,000mg/L
o-tolylchloride
2-Chlorotoluene [-8]
Clotrimazole Impurity 14
2-Chlorotoluene (1mg/ml in Methanol) [for Water Analysis]
2-Chlorotoluene,[2H4]-2-Chlorotoluene,[2H7]-2-Chlorotoluene,NA,O-chlorotoluic acid,O-chlorotolualdehyde,Tetrabromoo-chlorotoluene,NA,Azodyes-Mix Kit, 24 Ccinogenic yl Amine Mix, ampoule of 1. in methanol, 6 amp/ pack, containing 50 μg/ml each component: 1ST1201, 1ST1202, 1ST1203, 1ST1204, 1ST1205, 1ST1206, 1ST1207, 1ST1208, 1ST1209, 1ST1210, 1ST1211, 1ST1212, 1ST1213, 1ST1214,Azodyes-Mix Kit, 24 Ccinogenic yl Amine Mix, ampoule of 1. in methanol, 1 ampoule / package, containing
Halso 99
2-Chlorotoluene >
8 2-Chlorotoluene
Toluene,o-chloro
Benzyl Alcohol Impurity G
halso99
1-chloro-2-methyl-benzen
2-tolyl chloride
2-CHLOROTOLUENE PESTANAL
TOLUENE,ORTHO-CHLORO
markiertes Capsaicin
1,2-CHLOROTOLUENE
2-CHLOROTOLUENE
o-methylchlorobenzne
6-Nonenamide,N-((3,4-dimethoxyphenyl)methyl)-8-methyl-,(E)
2-CHLOROTOLUENE / 2-CHLORO-1-METHYLBENZENE
2-ChlorotolueneSolution,5,000mg/L
MFCD00000562
toluene,2-chloro
ortho-chlorotoluene
2-Chlorotoluene ISO 9001：2015 REACH
ortho-Chlorotoluene
Methylcapsaicin
2-ChlorotolueneSolution,2,000mg/L
o-chloro-toluen
2-CHLOROTOLUENE(OCT)
Human Octreotide
2-Chlorotoluene solution
o-Chlortoluol
o-Tolyl chloride
o-Chlorotoluene solution
2-Chlorotoluene Manufacturer kf-wang(at)kf-chem.com
o-Methylchlorobenzene
2-Chlorotoluene 1-Chloro-2-methylbenzene OCT
2,4-Dicyano-3-methylpentanediamide
2-Chlortoluol
1-Chloro-2-methylbenzene
o-Chlorotoluene
O-Clorotoluene
o-chlorotoluene
Density 1.082
Boiling Point 157-159 ºC
Melting Point -36 ºC
Molecular Formula C7H7Cl
Molecular Weight 126.584
Flash Point 47 ºC
Exact Mass 126.023628
LogP 3.27
Vapour density 4.38 (vs air)
Vapour Pressure 3.8±0.3 mmHg at 25°C
Index of Refraction 1.524-1.526
Water Solubility slightly soluble

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XS9000000
CHEMICAL NAME :
Toluene, o-chloro-
CAS REGISTRY NUMBER :
95-49-8
BEILSTEIN REFERENCE NO. :
1904175
LAST UPDATED :
199712
DATA ITEMS CITED :
28
MOLECULAR FORMULA :
C7-H7-Cl
MOLECULAR WEIGHT :
126.59
WISWESSER LINE NOTATION :
GR B1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3900 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - effect, not otherwise specified Behavioral - tremor Behavioral - excitement
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(10),56,1981
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
4400 ppm
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold Behavioral - ataxia Lungs, Thorax, or Respiration - respiratory stimulation
REFERENCE :
85INA8 "Documentation of the Threshold Limit Values and Biological Exposure Indices," 5th ed., Cincinnati, OH, American Conference of Governmental Industrial Hygienists, Inc., 1986 Volume(issue)/page/year: 6,308,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5700 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 45(12),64,1980
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2500 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - effect, not otherwise specified Behavioral - tremor Behavioral - excitement
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(10),56,1981
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
4400 ppm
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold Behavioral - ataxia Lungs, Thorax, or Respiration - respiratory stimulation
REFERENCE :
85INA8 "Documentation of the Threshold Limit Values and Biological Exposure Indices," 5th ed., Cincinnati, OH, American Conference of Governmental Industrial Hygienists, Inc., 1986 Volume(issue)/page/year: 6,308,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
4400 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 45(12),64,1980
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
4400 ppm
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold Behavioral - ataxia Lungs, Thorax, or Respiration - respiratory stimulation
REFERENCE :
85INA8 "Documentation of the Threshold Limit Values and Biological Exposure Indices," 5th ed., Cincinnati, OH, American Conference of Governmental Industrial Hygienists, Inc., 1986 Volume(issue)/page/year: 6,308,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
3 gm/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - excitement Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 46(2),67,1981 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
35910 mg/kg/9W-I
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 46(2),67,1981 *** REVIEWS *** ACGIH TLV-TWA 259 mg/m3 (50 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 50 ppm (250 mg/m3);STEL 75 ppm (375 mg/m3) JAN 1993 OEL-BELGIUM:TWA 50 ppm (259 mg/m3);STEL 75 ppm (388 mg/m3) JAN 1993 OEL-DENMARK:TWA 50 ppm (250 mg/m3);Skin JAN 1993 OEL-FINLAND:TWA 50 ppm (260 mg/m3);STEL 75 ppm (390 mg/m3);Skin JAN 1993 OEL-FRANCE:TWA 50 ppm (250 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 50 ppm (250 mg/m3);Skin JAN 1993 OEL-RUSSIA:STEL 10 mg/m3;Skin JAN 1993 OEL-SWITZERLAND:TWA 50 ppm (250 mg/m3);Skin JAN 1993 OEL-UNITED KINGDOM:TWA 50 ppm (250 mg/m3) JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO o-CHLOROTOLUENE-air:10H TWA 50 ppm;STEL 75 ppm REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X1254 No. of Facilities: 62 (estimated) No. of Industries: 2 No. of Occupations: 8 No. of Employees: 11617 (estimated) No. of Female Employees: 963 (estimated)
Symbol GHS02 GHS06 GHS08
GHS02, GHS06, GHS08
Signal Word Danger
Hazard Statements H225-H301 + H311 + H331-H360-H370
Precautionary Statements P201-P210-P260-P280-P301 + P310 + P330-P308 + P311-P403 + P233
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)
Hazard Codes Xn:Harmful
Risk Phrases R20;R51/53
Safety Phrases S24/25-S61-S45-S36/37-S16-S7
RIDADR UN 2238 3/PG 3
WGK Germany 2
RTECS XS9000000
Packaging Group III
Hazard Class 3
HS Code 29036990
HS Code 2903999090
Summary 2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
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