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815-82-7

815-82-7 structure
815-82-7 structure

Name Copper(II) (2R,3R)-2,3-dihydroxysuccinate
Synonyms DL-Tartaric acid
copper,(2R,3R)-2,3-dihydroxybutanedioate
2,3-Dihydroxy-succinic acid
2,3-dihydroxysuccinic acid
Tartaric acid, (±)-
2,3-dihydroxybutanedioic acid
Butanedioic acid, 2,3-dihydroxy-
Tartaric acid
Tartaric acid, (DL)-
EINECS 212-425-0
MFCD00150650
Density 1.9±0.1 g/cm3
Boiling Point 399.3±42.0 °C at 760 mmHg
Melting Point ~275 °C (dec.)(lit.)
Molecular Formula C4H4CuO6
Molecular Weight 150.087
Flash Point 209.4±24.4 °C
Exact Mass 150.016434
PSA 120.72000
LogP -1.43
Vapour Pressure 0.0±2.1 mmHg at 25°C
Index of Refraction 1.586
Water Solubility slightly soluble
Name: Copper(II) tartrate hydrate Material Safety Data Sheet
Synonym: Cupric tartrate hydrate; Butanedioic acid, 2,3-dihydroxy-(2R,3R)-, copper(2+) salt (1:1) hydrate
CAS: 815-82-7
Section 1 - Chemical Product MSDS Name:Copper(II) tartrate hydrate Material Safety Data Sheet
Synonym:Cupric tartrate hydrate; Butanedioic acid, 2,3-dihydroxy-(2R,3R)-, copper(2+) salt (1:1) hydrate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
815-82-7 Copper(II) tartrate hydrate 96 unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled.
Chronic:
May cause liver and kidney damage.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion:
Get medical aid. Wash mouth out with water. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If inhaled, remove to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid breathing dust.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 815-82-7: CAS# 5893-71-0: CAS# 17263-56-8: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystalline powder
Color: blue - green
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: decomposes
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density:
Molecular Formula: C4H4CuO6.xH2O
Molecular Weight: 211.62

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, oxides of copper.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 815-82-7 unlisted.
CAS# 5893-71-0 unlisted.
CAS# 17263-56-8 unlisted.
LD50/LC50:
Not available.
Not available.
Not available.
Carcinogenicity:
Copper(II) tartrate anhydrous - Not listed by ACGIH, IARC, or NTP.
Copper(II) tartrate trihydrate - Not listed by ACGIH, IARC, or NTP.
Copper(II) tartrate hydrate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
USA RQ: CAS# 815-82-7: 100 lb final RQ; 45.4 kg final RQ

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 815-82-7: No information available.
CAS# 5893-71-0: No information available.
CAS# 17263-56-8: No information available.
Canada
CAS# 815-82-7 is listed on Canada's DSL List.
CAS# 815-82-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 5893-71-0 is not listed on Canada's Ingredient Disclosure List.
CAS# 17263-56-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 815-82-7 is listed on the TSCA inventory.
CAS# 5893-71-0 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
CAS# 17263-56-8 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).


SECTION 16 - ADDITIONAL INFORMATION
N/A
Safety Phrases S24/25
RIDADR UN 9111
WGK Germany 3

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815-82-7 structure

815-82-7

Literature: Z. Anorg. Chem., , vol. 257, p. 340 - 348 Cu: MVol.B2, 72, page 781 - 783