| Name | 2-(1-Piperidino)aniline | 
|---|---|
| Synonyms | 
                                
                                2-(1-Piperidinyl)aniline
                                
                                
                                 2-(piperidin-1-yl)aniline 2-piperidin-1-ylaniline MFCD00047467 N-(2-Aminophenyl)piperidine Benzenamine, 2-(1-piperidinyl)-  | 
                        
| Density | 1.1±0.1 g/cm3 | 
|---|---|
| Boiling Point | 313.0±25.0 °C at 760 mmHg | 
| Melting Point | 44-48 °C | 
| Molecular Formula | C11H16N2 | 
| Molecular Weight | 176.258 | 
| Flash Point | 125.8±18.3 °C | 
| Exact Mass | 176.131348 | 
| PSA | 29.26000 | 
| LogP | 1.70 | 
| Vapour Pressure | 0.0±0.7 mmHg at 25°C | 
| Index of Refraction | 1.590 | 
                                
 Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS 
 Risk Phrases: 20/21/22 Section 3 - HAZARDS IDENTIFICATION   EMERGENCY OVERVIEW
 
                                    
                                Harmful by inhalation, in contact with skin and if swallowed. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. May cause respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 39643-31-7: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 96 deg C @1mmHg Freezing/Melting Point: 45 - 47 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C11H16N2 Molecular Weight: 176.26 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Oxidizing agents, strong acids. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 39643-31-7 unlisted. LD50/LC50: Not available. Carcinogenicity: 2-(1-Piperidino)aniline - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.* Hazard Class: 6.1 UN Number: 2811 Packing Group: III IMO Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing Group: III RID/ADR Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. Safety Phrases: S 36/37 Wear suitable protective clothing and gloves. WGK (Water Danger/Protection) CAS# 39643-31-7: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 39643-31-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 39643-31-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A  | 
                        
| Hazard Codes | Xn,T,Xi | 
|---|---|
| Risk Phrases | R20/21/22 | 
| Safety Phrases | S36/37 | 
| RIDADR | 2811 | 
| Packaging Group | III | 
| Hazard Class | 6.1 | 
| HS Code | 2933399090 | 
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                                 ~88%  
                                    39643-31-7  | 
                        
| Literature: HAGIWARA, Masatoshi Patent: EP1712242 A1, 2006 ; Location in patent: Page/Page column 44 ; | 
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                                 ~21%  
                                    39643-31-7  | 
                        
| Literature: Shvidenko, Tatyana; Nazarenko, Kostiantyn; Shvidenko, Konstantin; Kostyuk, Aleksandr Tetrahedron Letters, 2014 , vol. 55, # 1 p. 279 - 281 | 
| 
                                
                                
                                
                                
                                
                                
                                 ~%  
                                    39643-31-7  | 
                        
| Literature: Huisgen; Rist Justus Liebigs Annalen der Chemie, 1955 , vol. 594, p. 137,153 | 
| 
                                
                                
                                
                                
                                
                                
                                 ~%  
                                    39643-31-7  | 
                        
| Literature: Huisgen; Rist Justus Liebigs Annalen der Chemie, 1955 , vol. 594, p. 137,153 | 
| 
                                
                                
                                
                                
                                
                                
                                 ~%  
                                    39643-31-7  | 
                        
| Literature: Huisgen; Rist Justus Liebigs Annalen der Chemie, 1955 , vol. 594, p. 137,153 | 
| HS Code | 2933399090 | 
|---|---|
| Summary | 2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |