Name | Pentyl chloroformate |
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Synonyms |
Pentylchlorocarbonat
Chloroformic acid amyl ester Formic acid, chloro-, pentyl ester Pentyl chloridocarbonate n-Pentyl chloroformate Carbonochloridic acid, pentyl ester Amyl Chloroformate Pentyl carbonochloridate Formic acid, chloro-, pentyl ester (8CI) EINECS 211-336-4 MFCD00058933 |
Density | 1.1±0.1 g/cm3 |
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Boiling Point | 164.9±9.0 °C at 760 mmHg |
Molecular Formula | C6H11ClO2 |
Molecular Weight | 150.603 |
Flash Point | 47.7±11.9 °C |
Exact Mass | 150.044754 |
PSA | 26.30000 |
LogP | 3.03 |
Vapour Pressure | 1.9±0.3 mmHg at 25°C |
Index of Refraction | 1.426 |
Storage condition | Refrigerator |
Amyl Chloroformate
Revision number: 1
SAFETY DATA SHEET Section1. BASE INFORMATION Product name:Amyl Chloroformate Revision number:1 Section2. HAZARDS IDENTIFICATION Classification of the GHS PHYSICAL HAZARDS Flammable liquidsCategory 3 HEALTH HAZARDS Acute toxicity (Inhalation)Category 2 Category 1B Skin corrosion/irritation Serious eye damage/eye irritationCategory 1 Not classified ENVIRONMENTAL HAZARDS GHS label elements Pictograms or hazard symbols Signal wordDanger Hazard statementFlammable liquid and vapour Fatal if inhaled Causes severe skin burns and eye damage Precautionary statements Keep away from heat/sparks/open flames/hot surfaces. - No smoking. [Prevention] Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Take precautionary measures against ignition by the static discharge and the spark. Do not breathe. Use only outdoors or in a well-ventilated area. Wash hands thoroughly after handling. Wear respiratory protection. Wear protective gloves/eye protection/face protection. [Response]IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER or doctor/physician. Amyl Chloroformate Section2. HAZARDS IDENTIFICATION [Storage]Store in a well-ventilated place. Keep container tightly closed. Store locked up. [Disposal]Dispose of contents/container through a waste management company authorized by the local government Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/mixture:Substance Component(s):Amyl Chloroformate >97.0%(GC)(T) Percent: CAS Number:638-41-5 Chloroformic Acid Amyl Ester , Chloroformic Acid Pentyl Ester , Pentyl Chloroformate Synonyms: Chemical Formula:C6H11ClO2 Section4. FIRST AID MEASURES Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Skin contact:Remove/Take off immediately all contaminated clothing. Gently wash with plenty of soap and water. Immediately call a POISON CENTER or doctor/physician. Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Immediately call a POISON CENTER or doctor/physician. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT Ingestion: induce vomiting. Protection of first-aiders:A rescuer should wear personal protective equipment, such as rubber gloves and air- tight goggles. Section5. FIRE-FIGHTING MEASURES Suitable extinguishingDry chemical, carbon dioxide. media: Extinguishing media not to Water be used: Specific hazards:Take care as it may decompose upon combustion or in high temperatures to generate poisonous fume. Specific methods:Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Keep containers cool by spraying with water but NO direct contact with water. Eliminate all ignition sources if safe to do so. Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment. equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Personal precautions,Use extra personal protective equipment (self-contained breathing apparatus). Keep protective equipment and people away from and upwind of spill/leak. Ensure adequate ventilation. Entry to non- emergency procedures: involved personnel should be controlled around the leakage area by roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Absorb spilled material in dry sand or inert absorbent before recovering it into an containment and cleaning airtight container. In case of large amount of spillage, contain a spill by bunding. up: Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations. Prevention of secondary Do not allow contact with water. Remove all sources of ignition. Fire-extinguishing devices should be prepared in case of a fire. Use spark-proof tools and explosion- hazards: proof equipment. Section7. HANDLING AND STORAGE Handling Amyl Chloroformate Section7. HANDLING AND STORAGE Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment. Prevent generation of vapor or mist. Keep away from heat/sparks/open flame/hot surfaces. -No smoking. Take measures to prevent the build up of electrostatic charge. Use explosion-proof equipment. Wash hands and face thoroughly after handling. Use a closed system if possible. Use a ventilation, local exhaust if vapor or aerosol will be generated. Advice on safe handling: Avoid contact with skin, eyes and clothing. May develop pressure. Open carefully. Storage Storage conditions:Keep container tightly closed. Store in an explosion-poof refregerator. Store under inert gas. Protect from moisture. Store locked up. Store away from incompatible materials such as oxidizing agents. Packaging material:Law is followed. Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Install a closed system or local exhaust. Also install safety shower and eye bath. Engineering controls: Personal protective equipment Respiratory protection: Half or full facepiece respirator, self-contained breathing apparatus(SCBA), supplied air respirator, etc. Use respirators approved under appropriate government standards and follow local and national regulations. Hand protection:Impervious gloves. Eye protection:Safety goggles. A face-shield, if the situation requires. Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires. Section9. PHYSICAL AND CHEMICAL PROPERTIES Liquid Physical state (20°C): Form:clear Color:Colorless - Almost colorless No data available Odor: pH: No data available Melting point/freezing point:No data available Boiling Point/Range:161 °C No data available Flash Point: Explosive limits Lower:No data available Upper:No data available Density:1.03 Solubility:No data available Section10. STABILITY AND REACTIVITY Stable under proper conditions. Stability: Reactivity:Decomposes in contact with water and liberates toxic gases. Conditions to avoid:Heat-sensitive, Moisture-sensitive Incompartible materials: oxidizing agents, bases, water Hazardous Decomposition Carbon monoxide, Carbon dioxide, Hydrogen chloride Products: Section11. TOXICOLOGICAL INFORMATION Acute Toxicity:No data available Skin corrosion/irritation: No data available Serious eyeNo data available damage/irritation: Germ cell mutagenicity: No data available Amyl Chloroformate Section11. TOXICOLOGICAL INFORMATION Carcinogenicity: No data available IARC = NTP =No data available No data available Reproductive toxicity: Section12. ECOLOGICAL INFORMATION Ecotoxicity: Fish:No data available Crustacea:No data available Algae:No data available Persistence / degradability: No data available BioaccumulativeNo data available potential(BCF): Mobillity in soil log Pow:No data available Soil adsorption (Koc):No data available Henry's LawNo data available constant(PaM3/mol): Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when disposing of the substance. Section14. TRANSPORT INFORMATION Hazards Class:6.1: Toxic substance. Subsidiary risk:8: Corrosive. UN-No:3277 Proper shipping name:Chloroformates, toxic, corrosive, n.o.s. Packing group:II Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | C |
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Risk Phrases | R10 |
Safety Phrases | S26-S36-S45 |
RIDADR | 3277 |
Hazard Class | 6.1 |
HS Code | 2915900090 |
~83% 638-41-5 |
Literature: Shi, Haibo; Hu, Weixiao; Sun, Yaquan Journal of Chemical Research, 2004 , # 10 p. 708 - 709 |
~% 638-41-5 |
Literature: Journal of Organic Chemistry USSR (English Translation), , vol. 22, # 12 p. 2278 - 2286 Zhurnal Organicheskoi Khimii, , vol. 22, # 12 p. 2540 - 2548 |
HS Code | 2915900090 |
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Summary | 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0% |