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984-43-0

984-43-0 structure
984-43-0 structure

Name 1,2-bis(diphenylphosphino)ethane monooxide
Synonyms Tetraphenylethylenediphosphine monooxide
AURORA KA-1612
tetraphenylethylenediphosphine monoxide
MFCD00345406
Boiling Point 534.306ºC at 760 mmHg
Melting Point 195-199ºC(lit.)
Molecular Formula C26H24OP2
Molecular Weight 414.41600
Flash Point 276.938ºC
Exact Mass 414.13000
PSA 40.47000
LogP 5.13340
Appearance Powder | white

Section 1: Product Identification
Chemical Name:1,2-Bis(diphenylphosphino)ethane monooxide, min. 97%
CAS Registry Number:984-43-0
Formula:(C6H5)2PCH2CH2P(O)(C6H5)2
EINECS Number:none
Chemical Family:organophosphine ligand
Synonym:[2-(Diphenylphosphino)ethyl]diphenylphosphine oxide; [2-(Diphenyl-phosphinoyl)-ethyl]-diphenyl-phosphane

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound984-43-0100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract. May be harmful if swallowed.
Primary Routes of Exposure:Inhalation, skin, eyes.
Eye Contact:Causes moderate irritation of the eyes.
Skin Contact:Causes irritation of the skin. May cause redness, itching and pain.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No specific information is available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, dry powder or foam
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store the material in a cool, dry place in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white powder
Molecular Weight:414.42
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:not determined
Solubility in Water:no data

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:strong oxidizing agents and halogens
Decomposition Products:carbon monoxide, carbon dioxide, phosphorous pentoxide, and organic fumes.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
Personal Protective Equipment Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
Safety Phrases S22-S24/25
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2902909090

~84%

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984-43-0

Literature: Grushin, Vladimir V. Journal of the American Chemical Society, 1999 , vol. 121, # 24 p. 5831 - 5832

~88%

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984-43-0

Literature: Kabachnik, M. I.; Medved', T. Ya.; Pisareva, S. A.; Ignat'eva, T. I.; Lomakina, L. N.; et al. Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1980 , vol. 29, # 3 p. 495 - 500 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1980 , # 3 p. 673 - 678

~84%

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Literature: Petersson, Maria J.; Loughlin, Wendy A.; Jenkins, Ian D. Chemical Communications, 2008 , # 37 p. 4493 - 4494

~89%

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Literature: Bondarenko, N. A.; Rudomino, M. V.; Tsvetkov, E. N. Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1990 , vol. 39, # 9.2. p. 1989 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1990 , vol. 39, # 9 p. 2180 - 2181
HS Code 2902909090
Summary 2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%