18236-89-0

18236-89-0 structure
18236-89-0 structure

Name dichloro-methyl-propan-2-ylsilane
Synonyms Dichlor-isopropyl-methyl-silan
Isopropylmethyldichlorosilane
Dichlor-methyl-isopropyl-silan
MFCD00054830
Methylisopropyldichlorosilane
sNpLADQpTPduuUP@
Density 1.033
Boiling Point 121ºC
Molecular Formula C4H10Cl2Si
Molecular Weight 157.11400
Flash Point 14ºC
Exact Mass 155.99300
LogP 2.94600
Vapour Pressure 16.3mmHg at 25°C
Index of Refraction 1.425-1.428
Name: Isopropylmethyldichlorosilane 97% Material Safety Data Sheet
Synonym:
CAS: 18236-89-0
Section 1 - Chemical Product MSDS Name:Isopropylmethyldichlorosilane 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
18236-89-0 Isopropylmethyldichlorosilane 97% unlisted
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns.
Potential Health Effects
Eye:
Causes eye burns. May cause conjunctivitis. May cause blindness.
Contact with the eyes may cause corneal damage.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. Causes gastrointestinal tract burns. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes chemical burns to the respiratory tract. The toxicological properties of this substance have not been fully investigated.
Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema.
May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 18236-89-0: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Clear liquid
Color: colorless
Odor: hydrochloric odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 121 deg C @ 760 mmH
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Reacts.
Specific Gravity/Density: Not available.
Molecular Formula: (CH3)2CHSi(Cl)2CH3
Molecular Weight: 157.0615

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Water, oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, silicon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 18236-89-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Isopropylmethyldichlorosilane - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 18236-89-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 18236-89-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 18236-89-0 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes C: Corrosive;
Risk Phrases R34
Safety Phrases 45-36/37/39-25
RIDADR UN 2985
HS Code 2931900090

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18236-89-0

Literature: Bulletin of the Chemical Society of Japan, , vol. 61, # 7 p. 2369 - 2381

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18236-89-0

Literature: Zhurnal Obshchei Khimii, , vol. 27, p. 2062; engl.Ausg.S. 2117

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18236-89-0 structure

18236-89-0

Literature: Zhurnal Obshchei Khimii, , vol. 27, p. 2062; engl.Ausg.S. 2117

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18236-89-0 structure

18236-89-0

Literature: Journal of Organometallic Chemistry, , vol. 692, # 17 p. 3700 - 3705

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18236-89-0 structure

18236-89-0

Literature: Bulletin de l'Academie Polonaise des Sciences, Serie des Sciences Chimiques, , vol. 12, p. 281 - 287
HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%