Name | dichloro-methyl-propan-2-ylsilane |
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Synonyms |
Dichlor-isopropyl-methyl-silan
Isopropylmethyldichlorosilane Dichlor-methyl-isopropyl-silan MFCD00054830 Methylisopropyldichlorosilane sNpLADQpTPduuUP@ |
Density | 1.033 |
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Boiling Point | 121ºC |
Molecular Formula | C4H10Cl2Si |
Molecular Weight | 157.11400 |
Flash Point | 14ºC |
Exact Mass | 155.99300 |
LogP | 2.94600 |
Vapour Pressure | 16.3mmHg at 25°C |
Index of Refraction | 1.425-1.428 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Causes burns. Potential Health Effects Eye: Causes eye burns. May cause conjunctivitis. May cause blindness. Contact with the eyes may cause corneal damage. Skin: Causes skin burns. Ingestion: Causes gastrointestinal irritation with nausea, vomiting and diarrhea. Causes gastrointestinal tract burns. The toxicological properties of this substance have not been fully investigated. Inhalation: Causes chemical burns to the respiratory tract. The toxicological properties of this substance have not been fully investigated. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Corrosives area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 18236-89-0: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Clear liquid Color: colorless Odor: hydrochloric odor pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 121 deg C @ 760 mmH Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not applicable. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Reacts. Specific Gravity/Density: Not available. Molecular Formula: (CH3)2CHSi(Cl)2CH3 Molecular Weight: 157.0615 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Water, oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, carbon dioxide, silicon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 18236-89-0 unlisted. LD50/LC50: Not available. Carcinogenicity: Isopropylmethyldichlorosilane - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 34 Causes burns. Safety Phrases: S 16 Keep away from sources of ignition - No smoking. S 25 Avoid contact with eyes. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 18236-89-0: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 18236-89-0 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 18236-89-0 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | C: Corrosive; |
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Risk Phrases | R34 |
Safety Phrases | 45-36/37/39-25 |
RIDADR | UN 2985 |
HS Code | 2931900090 |
~% 18236-89-0 |
Literature: Bulletin of the Chemical Society of Japan, , vol. 61, # 7 p. 2369 - 2381 |
~% 18236-89-0 |
Literature: Zhurnal Obshchei Khimii, , vol. 27, p. 2062; engl.Ausg.S. 2117 |
~% 18236-89-0 |
Literature: Zhurnal Obshchei Khimii, , vol. 27, p. 2062; engl.Ausg.S. 2117 |
~% 18236-89-0 |
Literature: Journal of Organometallic Chemistry, , vol. 692, # 17 p. 3700 - 3705 |
~% 18236-89-0 |
Literature: Bulletin de l'Academie Polonaise des Sciences, Serie des Sciences Chimiques, , vol. 12, p. 281 - 287 |
HS Code | 2931900090 |
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Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |