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83-66-9

83-66-9 structure
83-66-9 structure
Name musk ambrette
Synonyms 5-tert-Butyl-1,3-dinitro-4-methoxy-2-methylbenzene
EINECS 201-493-7
2-tert-butyl-5-methyl-4,6-dinitroanisole
4-tert-Butyl-2,6-dinitro-3-methoxytoluene
6-tert-Butyl-3-methyl-2,4-dinitroanisol
syntheticmuskambrette
2-Methoxy-4-methyl-1-(2-methyl-2-propanyl)-3,5-dinitrobenzene
6-tert-Butyl-3-methyl-2,4-dinitrophenyl methyl ether
AMBRETTEMUSKRESIDUES
1-tert-butyl-2-methoxy-4-methyl-3,5-dinitro-benzene
artificialmuskambrette
Benzene, 1- (1,1-dimethylethyl)-2-methoxy-4-methyl-3,5-dinitro-
MOSCHUS-AMBRETTE
ambermust
Musk amberette
1-tert-Butyl-2-methoxy-4-methyl-3,5-dinitrobenzol
Amber musk
Ambrottolide
6-tert-butyl-3-methyl-2,4-dinitro-anisole
1-tert-butyl-2-methoxy-4-methyl-3,5-dinitrobenzene
6-tert-Butyl-3-methyl-2,4-dinitro-anisol
Benzene, 1-(1,1-dimethylethyl)-2-methoxy-4-methyl-3,5-dinitro-
ambrettemusk
musk ambrette
MFCD00024268
Density 1.2±0.1 g/cm3
Boiling Point 369.3±42.0 °C at 760 mmHg
Melting Point 84-86°C
Molecular Formula C12H16N2O5
Molecular Weight 268.266
Flash Point 149.6±29.9 °C
Exact Mass 268.105927
PSA 100.87000
LogP 3.71
Vapour Pressure 0.0±0.8 mmHg at 25°C
Index of Refraction 1.542

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BZ8575000
CHEMICAL NAME :
Anisole, 6-t-butyl-3-methyl-2,4-dinitro-
CAS REGISTRY NUMBER :
83-66-9
BEILSTEIN REFERENCE NO. :
1889437
LAST UPDATED :
199806
DATA ITEMS CITED :
15
MOLECULAR FORMULA :
C12-H16-N2-O5
MOLECULAR WEIGHT :
268.30
WISWESSER LINE NOTATION :
WNR B1 DO1 CNW EX1&1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
339 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - respiratory stimulation Skin and Appendages - hair
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
10500 mg/kg/20W-I
TOXIC EFFECTS :
Behavioral - muscle weakness Musculoskeletal - other changes Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
6300 mg/kg/12W-C
TOXIC EFFECTS :
Brain and Coverings - demyelination Spinal Cord - demyelination Peripheral Nerve and Sensation - structural change in nerve or sheath
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
6750 mg/kg/90D-I
TOXIC EFFECTS :
Spinal Cord - demyelination Peripheral Nerve and Sensation - structural change in nerve or sheath Related to Chronic Data - changes in testicular weight

MUTATION DATA

TEST SYSTEM :
Insect - Drosophila melanogaster
DOSE/DURATION :
10 mmol/L
REFERENCE :
FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 21,707,1983 *** REVIEWS *** IARC Cancer Review:Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 65,477,1996 IARC Cancer Review:Human Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 65,477,1996 IARC Cancer Review:Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 65,477,1996 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83003 No. of Facilities: 260 (estimated) No. of Industries: 4 No. of Occupations: 20 No. of Employees: 23082 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83003 No. of Facilities: 1567 (estimated) No. of Industries: 11 No. of Occupations: 16 No. of Employees: 22736 (estimated) No. of Female Employees: 16492 (estimated)
Hazard Codes Xn
Risk Phrases R20/21/22
Safety Phrases S26-S36/37/39
RIDADR 2811
RTECS BZ8575000
HS Code 2909309090
88-40-4 structure

88-40-4

~46%

83-66-9 structure

83-66-9

3606-21-1 structure

3606-21-1

Literature: Synthesis, , # 8 p. 1291 - 1293
88-40-4 structure

88-40-4

~82%

83-66-9 structure

83-66-9

Literature: Safaei-Ghomi, Javad; Bamoniri, Abdolhamid Organic Preparations and Procedures International, 2004 , vol. 36, # 2 p. 188 - 191
71850-79-8 structure

71850-79-8

~%

83-66-9 structure

83-66-9

3606-21-1 structure

3606-21-1

Literature: Zhurnal Obshchei Khimii, , vol. 2, p. 472,475 Chem. Zentralbl., , vol. 104, # I p. 604
100-84-5 structure

100-84-5

~%

83-66-9 structure

83-66-9

Literature: Chemische Berichte, , vol. 27, p. 1606 Chemische Berichte, , vol. 24, p. 2832
77-78-1 structure

77-78-1

~%

83-66-9 structure

83-66-9

Literature: Bulletin de la Societe Chimique de France, , vol. <5> 4, p. 439
874521-29-6 structure

874521-29-6

7697-37-2 structure

7697-37-2

~%

83-66-9 structure

83-66-9

3606-21-1 structure

3606-21-1

Detail
Literature: US1926080 , ; Journal of Organic Chemistry, , vol. 16, p. 586,606
88-40-4 structure

88-40-4

7697-37-2 structure

7697-37-2

108-24-7 structure

108-24-7

~%

83-66-9 structure

83-66-9

Detail
Literature: Zhurnal Obshchei Khimii, , vol. 2, p. 472,475 Chem. Zentralbl., , vol. 104, # I p. 604 Zhurnal Obshchei Khimii, , vol. 7, p. 2183,2187 Chem. Zentralbl., , vol. 109, # I p. 3909 US2007234 , ;
71850-79-8 structure

71850-79-8

7697-37-2 structure

7697-37-2

~%

83-66-9 structure

83-66-9

3606-21-1 structure

3606-21-1

Literature: Zhurnal Obshchei Khimii, , vol. 2, p. 472,475 Chem. Zentralbl., , vol. 104, # I p. 604
88-40-4 structure

88-40-4

7697-37-2 structure

7697-37-2

64-19-7 structure

64-19-7

~%

83-66-9 structure

83-66-9

Detail
Literature: Helvetica Chimica Acta, , vol. 11, p. 155 DE62362 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 3, p. 879 Zhurnal Obshchei Khimii, , vol. 2, p. 472,475 Chem. Zentralbl., , vol. 104, # I p. 604 Chemische Berichte, , vol. 27, p. 1606 Chemische Berichte, , vol. 24, p. 2832
HS Code 2909309090
Summary 2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
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