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35691-65-7

35691-65-7 structure
35691-65-7 structure

Name 2-bromo-2-(bromomethyl)pentanedinitrile
Synonyms 1-Bromo-1-(bromomethyl)-1,3-propanedicarbonitrile
(2RS)-2-bromo-2-(bromomethyl)glutaronitrile
Methyldibromoglutaronitrile
1,2-Dibromo-2,4-dicyanobutane
Metacide 38
1-Bromo-1-(bromomethyl)propane-1,3-dicarbonitrile
2-bromo-2-(bromomethyl)-glutaronitrile
Tektamer 38AD
Tektamer
Pentanedinitrile, 2-bromo-2-(bromomethyl)-
2-bromo-2-(bromomethyl)-pentandinitrile
Methyldibromo glutaronitrile
Tektamer 38
2-Bromo-2-(bromomethyl)glutaronitrile
EINECS 252-681-0
MFCD00072483
Bromothalonil
2-bromo-2-(bromomethyl)-pentanedinitrile
NC2XECN&1E
2-Bromo-2-(bromomethyl)pentanedinitrile
Density 1.9±0.1 g/cm3
Boiling Point 338.6±42.0 °C at 760 mmHg
Melting Point 48-50°C
Molecular Formula C6H6Br2N2
Molecular Weight 265.933
Flash Point 158.6±27.9 °C
Exact Mass 263.889771
PSA 47.58000
LogP 1.71
Vapour Pressure 0.0±0.7 mmHg at 25°C
Index of Refraction 1.554
Storage condition 2-8°C

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MA5599000
CHEMICAL NAME :
Glutaronitrile, 2-bromo-2-(bromomethyl)-
CAS REGISTRY NUMBER :
35691-65-7
LAST UPDATED :
199712
DATA ITEMS CITED :
13
MOLECULAR FORMULA :
C6-H6-Br2-N2
MOLECULAR WEIGHT :
265.96

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
JACTDZ Journal of the American College of Toxicology. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1-12, 1982-1993. Discontinued. Volume(issue)/page/year: 15,140,1996
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
JACTDZ Journal of the American College of Toxicology. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1-12, 1982-1993. Discontinued. Volume(issue)/page/year: 15,140,1996 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
515 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JACTDZ Journal of the American College of Toxicology. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1-12, 1982-1993. Discontinued. Volume(issue)/page/year: 15,140,1996
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>13 gm/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JACTDZ Journal of the American College of Toxicology. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1-12, 1982-1993. Discontinued. Volume(issue)/page/year: 15,140,1996
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JACTDZ Journal of the American College of Toxicology. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1-12, 1982-1993. Discontinued. Volume(issue)/page/year: 15,140,1996 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
84 gm/kg/3W-I
TOXIC EFFECTS :
Blood - pigmented or nucleated red blood cells Blood - changes in erythrocyte (RBC) count Skin and Appendages - dermatitis, other (after systemic exposure)
REFERENCE :
JACTDZ Journal of the American College of Toxicology. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1-12, 1982-1993. Discontinued. Volume(issue)/page/year: 15,140,1996
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
380 mg/kg/13W-C
TOXIC EFFECTS :
Endocrine - changes in thyroid weight
REFERENCE :
JACTDZ Journal of the American College of Toxicology. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1-12, 1982-1993. Discontinued. Volume(issue)/page/year: 15,140,1996
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
120 mg/kg/4W-I
TOXIC EFFECTS :
Blood - pigmented or nucleated red blood cells
REFERENCE :
JACTDZ Journal of the American College of Toxicology. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1-12, 1982-1993. Discontinued. Volume(issue)/page/year: 15,140,1996 ** REPRODUCTIVE DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
1750 mg/kg
SEX/DURATION :
female 6-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants)
REFERENCE :
TOLED5 Toxicology Letters. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1977- Volume(issue)/page/year: 18(Suppl 1),158,1983 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X1017 No. of Facilities: 512 (estimated) No. of Industries: 9 No. of Occupations: 10 No. of Employees: 17713 (estimated) No. of Female Employees: 3345 (estimated)
Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger
Hazard Statements H302-H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes Xn
Risk Phrases R22;R36/37/38
Safety Phrases S26-S36/37/39-S45
RIDADR 3439
RTECS MA5599000
Packaging Group III
Hazard Class 9
HS Code 2926909038
Precursor  1

DownStream  1

HS Code 2926909038
Summary HS: 2926909038 fenoxanil Educational tariff:17.0% Tax rebate rate:9.0% Regulatory conditions:S(Registration certificate of import and export) Lowest tariff:6.5% General tariff:30.0%