Name | 2-ethylhexanoyl 2-ethylhexanoate |
---|---|
Synonyms |
1-Ethylhexanoic anhydride
TVPCUVQDVRZTAL-UHFFFAOYSA EINECS 253-195-1 2-ethylhexanoyl anhydride 2-ethyl-hexanoic acid-anhydride 2-Aethyl-hexansaeure-anhydrid (2-Ethyl-hexansaeure)-anhydrid Hexanoic acid,2-ethyl-,anhydride 2-ethylhexanoic anhydride MFCD00043963 |
Density | 0.919g/cm3 |
---|---|
Boiling Point | 300.3ºC at 760mmHg |
Molecular Formula | C16H30O3 |
Molecular Weight | 270.40800 |
Flash Point | 135.8ºC |
Exact Mass | 270.21900 |
PSA | 43.37000 |
LogP | 4.48900 |
Index of Refraction | 1.4335-1.4355 |
Synonym: None. SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin.Moisture sensitive. Potential Health Effects Eye: Causes eye irritation. May cause chemical conjunctivitis. Skin: Causes skin irritation.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Inhalation: Causes respiratory tract irritation. Can produce delayed pulmonary edema. Chronic: Effects may be delayed. SECTION 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. Notes to Physician: Treat symptomatically and supportively. SECTION 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Do NOT get water inside containers. Use water spray, dry chemical, carbon dioxide, or appropriate foam. SECTION 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Provide ventilation. Do not get water inside containers. SECTION 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Use with adequate ventilation. Do not allow contact with water. Keep from contact with moist air and steam. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture. SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 36765-89-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: yellow orange Odor: none reported pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 163 deg C @ 16.00 mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not applicable. Flash Point: > 212 deg C (> 413.60 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Not available. Solubility in water: negligible Specific Gravity/Density: Not available. Molecular Formula: C16H30O3 Molecular Weight: 270.40 SECTION 10 - STABILITY AND REACTIVITY Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Moisture sensitive. Conditions to Avoid: Incompatible materials, moisture, excess heat, strong oxidants. Incompatibilities with Other Materials: Moisture, strong oxidizing agents. Hazardous Decomposition Products: Irritating and toxic fumes and gases. Hazardous Polymerization: Has not been reported SECTION 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 36765-89-6 unlisted. LD50/LC50: Not available. Carcinogenicity: 2-ethylhexanoic anhydride - Not listed by ACGIH, IARC, or NTP. SECTION 12 - ECOLOGICAL INFORMATION SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. SECTION 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. SECTION 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 36765-89-6: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 36765-89-6 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 36765-89-6 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages. SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | Xi: Irritant; |
---|---|
Risk Phrases | 36/37/38 |
Safety Phrases | 24/25 |
HS Code | 2915900090 |
~95% 36765-89-6 |
Literature: Cabre-Castellvi, J.; Palomo-Coll, A.; Palomo-Coll, A.L. Synthesis, 1981 , # 8 p. 616 - 620 |
~0% 36765-89-6 |
Literature: Gros, P.; Perchec, P. Le; Gauthier, P.; Senet, J. P. Bulletin de la Societe Chimique de France, 1993 , vol. 130, p. 554 - 561 |
~19% 36765-89-6 |
Literature: Gros, P.; Perchec, P. Le; Gauthier, P.; Senet, J. P. Bulletin de la Societe Chimique de France, 1993 , vol. 130, p. 554 - 561 |
~% 36765-89-6 |
Literature: Vrbaski; Brihta Arhiv za Kemiju, 1952 , vol. 24, p. 111,117 Chem.Abstr., 1955 , p. 163 |
~% 36765-89-6 |
Literature: Vrbaski; Brihta Arhiv za Kemiju, 1952 , vol. 24, p. 111,117 Chem.Abstr., 1955 , p. 163 |
~% 36765-89-6 |
Literature: Vrbaski; Brihta Arhiv za Kemiju, 1952 , vol. 24, p. 111,117 Chem.Abstr., 1955 , p. 163 |
HS Code | 2915900090 |
---|---|
Summary | 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0% |