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14267-08-4

14267-08-4 structure
14267-08-4 structure

Name Dichloro(N,N,N′,N′-tetramethylethylenediamine)palladium(II)
Synonyms DICHLORO(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)PALLADIUM(II)
MFCD00075317
Palladium(2+) chloride - N,N,N',N'-tetramethyl-1,2-ethanediamine (1:2:1)
Palladium,dichloro(N,N,N',N'-tetramethyl-1,2-ethanediamine-N,N')-,(sp-4-2)
(N,N,N',N'-tetramethylethylenediamine)PdCl2
dichloro(N,N,N',N'-tetramethylethylene-diamine)pa
[Pd(tmen)Cl2]
N,N,N',N'-tetramethylethylenediamine palladium(II) chloride
Palladium,dichloro(N,N,N',N'-tetramethylethylenediamine)
cis-dichloro(N,N,N',N'-tetramethylethylenediamine)palladium(II)
Cl2Pd(II)(TMEDA)
1,2-Ethanediamine, N,N,N,N-tetramethyl-, palladium(2+) salt, hydrochloride (1:1:2)
(N,N,N',N'-tetramethylethylenediamine)dichloridopalladium(II)
Boiling Point 121ºC at 760 mmHg
Melting Point 245ºC (dec.)(lit.)
Molecular Formula C6H16Cl2N2Pd
Molecular Weight 293.531
Flash Point 10ºC
Exact Mass 291.972534
PSA 6.48000
LogP 1.48860
Vapour Pressure 14.9mmHg at 25°C

Section 1: Product Identification
Chemical Name:cis-Dichloro(N,N,N'N'-tetramethylethylenediamine)palladium(II), 99%
CAS Registry Number:14267-08-4
Formula:C6H16Cl2N2Pd
EINECS Number:none
Chemical Family:organometallic complex
Synonym:cis-ichloroN,N,N',N'-Tetramethyl-ethane-1,2-diamine)palladium(II)

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound14267-08-4100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure:Ingestion, inhalation
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, dry powder or foam
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a tightly sealed container. Keep in a cool, dry, well ventilated place.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:yellow powder
Molecular Weight:293.53
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:not determined
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:strong oxidizing agents
Decomposition Products:carbon monoxide, carbon dioxide, palladium oxide and organic fumes

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory
SARA (Title 313):Title compound not listed
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases 37/39-26
RIDADR NONH for all modes of transport

~98%

14267-08-4 structure

14267-08-4

Literature: Biscoe, Mark R.; Fors, Brett P.; Buchwald, Stephen L. Journal of the American Chemical Society, 2008 , vol. 130, # 21 p. 6686 - 6687

~97%

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Literature: Zhao, Qing; Li, Chengxi; Senanayake, Chris H.; Tang, Wenjun Chemistry - A European Journal, 2013 , vol. 19, # 7 p. 2261 - 2265

~90%

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Literature: Graaf, Wim de; Boersma, Jaap; Smeets, Wilberth J. J.; Spek, Anthony L.; Koten, Gerard van Organometallics, 1989 , vol. 8, p. 2907 - 2917

~97%

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Literature: Jung, Miso; Suzaki, Yuji; Saito, Takashi; Shimada, Kyoichi; Osakada, Kohtaro Polyhedron, 2012 , vol. 40, # 1 p. 168 - 174

~%

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14267-08-4

Literature: Inorganic Chemistry, , vol. 31, p. 1090 - 1095

~%

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14267-08-4

Literature: Polyhedron, , vol. 19, # 8 p. 959 - 963

~%

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14267-08-4

Literature: Inorganica Chimica Acta, , vol. 188, p. 25 - 32

~%

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Literature: Inorganica Chimica Acta, , vol. 198 - 200, p. 187 - 192