Shanghai Jizhi Biochemical Technology Co., Ltd
China
Product Name: benthiocarb
Price: ￥638.0/250mg
Purity: 98.0%
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Contact: Liu jia

DC Chemicals Limited
China
Product Name: Thiobencarb
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Purity: 98.0%
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Dayang Chem (Hangzhou) Co., Ltd.
China
Product Name: Thiobencarb
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Zhejiang Hangyu API Co., Ltd
China
Product Name: Thiobencarb
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Purity: 99.5%
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Contact: Vinnie

Henan Tianfu Chemical Co., Ltd.
China
Product Name: thiobencarb
Price: $Inquiry/1kg $Inquiry/25kg $Inquiry/1000kg $Inquiry/10ton
Purity: 99.0%
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Contact: Anson

28249-77-6

28249-77-6 structure

Name: benthiocarb
Chemical Name: thiobencarb
CAS Number: 28249-77-6
Molecular Formula: C₁₂H₁₆ClNOS
Molecular Weight: 257.78
Catalog: Chemical pesticide herbicide Carbamate herbicide
Create Date: 2018-03-11 08:00:00
Modify Date: 2024-01-02 15:44:45
Thiobencarb is an herbicide, can reduce growth, photosynthetic activity, and amount of rieske iron-sulfur protein in the diatom Thalassiosira pseudonana[1].

Name	thiobencarb
Synonyms	Carbamothioic acid, N,N-diethyl-, S-[(4-chlorophenyl)methyl] ester Saturno EINECS 248-924-5 S-[(4-Chlorophenyl)methyl] Diethylcarbamothioate S-4-chlorobenzyl N,N-diethylthiocarbamate Saturn S-[(4-chlorophenyl)methyl] N,N-diethylcarbamothioate benthiocarb Bencarb Bolero Siacarb MFCD00055475 Thiobencarb S-p-chlorobenzyl diethylthiocarbamate S-4-Chlorobenzyl Diethyl(thiocarbamate) Carbamothioic acid, diethyl-, S-[(4-chlorophenyl)methyl] ester S-(p-Chlorobenzyl) diethylthiocarbamate (8CI) S-(4-chlorobenzyl) diethylthiocarbamate Bolero 8EC Caswell No. 207DA S-4-chlorobenzyl diethylthiocarbamate S-(4-Chlorobenzyl) diethylcarbamothioate

Description	Thiobencarb is an herbicide, can reduce growth, photosynthetic activity, and amount of rieske iron-sulfur protein in the diatom Thalassiosira pseudonana[1].
Related Catalog	Research Areas >> Others Signaling Pathways >> Others >> Others
References	[1]. Shimasaki Y, et al. Thiobencarb herbicide reduces growth, photosynthetic activity, and amount of Rieske iron-sulfur protein in the diatom Thalassiosira pseudonana. J Biochem Mol Toxicol. 2013 Sep;27(9):437-44.

Density	1.2±0.1 g/cm3
Boiling Point	350.5±44.0 °C at 760 mmHg
Melting Point	3.3ºC
Molecular Formula	C₁₂H₁₆ClNOS
Molecular Weight	257.78
Flash Point	165.8±28.4 °C
Exact Mass	257.064117
PSA	45.61000
LogP	3.53
Vapour Pressure	0.0±0.8 mmHg at 25°C
Index of Refraction	1.563

CHEMICAL IDENTIFICATION

RTECS NUMBER :: EZ7260000

CHEMICAL NAME :: Carbamic acid, diethylthio-, S-(p-chlorobenzyl) ester

CAS REGISTRY NUMBER :: 28249-77-6

LAST UPDATED :: 199706

DATA ITEMS CITED :: 13

MOLECULAR FORMULA :: C12-H16-Cl-N-O-S

MOLECULAR WEIGHT :: 257.80

WISWESSER LINE NOTATION :: GR B1SVN2&2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 920 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >7700 mg/m3/4H

TOXIC EFFECTS :: Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Sense Organs and Special Senses (Eye) - lacrimation

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2900 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 560 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 10 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1338 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >2 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - chicken

DOSE/DURATION :: 673 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - quail

DOSE/DURATION :: >7800 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - duck

DOSE/DURATION :: >10 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 300 ug/plate

REFERENCE :: JAFCAU Journal of Agricultural and Food Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC 20037) V.1- 1953- Volume(issue)/page/year: 45,990,1997 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

Symbol	GHS07, GHS09
Signal Word	Warning
Hazard Statements	H302-H410
Precautionary Statements	P273-P501
Personal Protective Equipment	Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes	Xi:Irritant;
Risk Phrases	R22;R50/53
Safety Phrases	S60-S61
RIDADR	UN 3082
WGK Germany	3.0
RTECS	EZ7260000
Hazard Class	9.0
HS Code	2930200011

201230-82-2

104-83-6

109-89-7

~98%

28249-77-6

Literature: Mizuno, Takumi; Iwai, Toshiyuki; Ishino, Yoshio Tetrahedron, 2005 , vol. 61, # 38 p. 9157 - 9163

109-89-7

534572-34-4

~91%

28249-77-6

Literature: Wynne, James H.; Jensen, Samuel D.; Snow, Arthur W. Journal of Organic Chemistry, 2003 , vol. 68, # 9 p. 3733 - 3735

2430-00-4

6258-66-8

~54%

28249-77-6

Literature: Wynne, James H.; Jensen, Samuel D.; Snow, Arthur W. Journal of Organic Chemistry, 2003 , vol. 68, # 9 p. 3733 - 3735

104-83-6

22318-01-0

28249-77-6

Literature: Mizuno, Takumi; Iwai, Toshiyuki; Ito, Takatoshi Tetrahedron, 2004 , vol. 60, # 12 p. 2869 - 2873

463-58-1

104-83-6

109-89-7

28249-77-6

Literature: Chin-Hsien, Wang Synthesis, 1981 , # 8 p. 622 - 623

6258-66-8

28249-77-6

Literature: Wynne, James H.; Jensen, Samuel D.; Snow, Arthur W. Journal of Organic Chemistry, 2003 , vol. 68, # 9 p. 3733 - 3735

Precursor 7
201230-82-2 104-83-6 109-89-7 534572-34-4
2430-00-4 6258-66-8 463-58-1
DownStream 6
39918-94-0 50586-77-1 104-88-1 6258-66-8
873-76-7 75-04-7

HS Code	2930200011
Summary	2930200011 s,s'-(2-(dimethylamino)propane-1,3-diyl) dicarbamothioate。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%