Name | bis(oxomethylidene)titanium,cyclopenta-1,3-diene |
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Synonyms | MFCD00143762 |
Boiling Point | 60ºC/0.001mm |
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Melting Point | 90ºC |
Molecular Formula | C12H10O2Ti |
Molecular Weight | 234.07400 |
Flash Point | 60°C/0.001mm subl. |
Exact Mass | 234.01600 |
LogP | 1.62700 |
Appearance | crystal | red |
Water Solubility | Insoluble in water. |
Section 1: Product Identification Chemical Name:Bis(cyclopentadienyl)dicarbonyl titanium(II), min. 98% CAS Registry Number:12129-51-0 Formula:(C5H5)2Ti(CO)2 EINECS Number:none Chemical Family:metallocene Titanium, bis[(1,2,3,4,5-.eta.)-2,4-cyclopentadiene-1-yl]dicarbonyl, Dicarbonylbiscyclopentadienyl titanium,
Synonym: Titanocene dicarbonyl Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound12129-51-0100%no datano data Section 3: Hazards Identification Emergency Overview:No particular hazard associated with this material. Primary Routes of Exposure:Ingestion Eye Contact:May cause slight to mild irritation of the eyes. Skin Contact:May cause slight to mild irritation of the skin. Inhalation:May be irritating to the nose, mucous membranes and respiratory tract. Ingestion:No information on the physiological effects of ingestion. Acute Health Affects:May be irritating to skin, eyes and respiratory tract. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in Inhalation: breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:carbon dioxide or dry powder If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus. Hazardous Combustion andIf involved in a fire this product may emit toxic and corrosive fumes. Decomposion Products: Unusual Fire or Explosion Hazards: Flammable solid SECTION 6: Accidental Release Measures Spill and Leak Procedures:Remove sources of ignition. do not raise dust. sweep up the solids and dispose of properly. SECTION 7: Handling and Storage Handle and store the material under an inert atmosphere of nitrogen or argon. Keep away from heat and Handling and Storage: moisture. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:red xtl Molecular Weight:234.09 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:not determined Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air sensitive Hazardous Polymerization:No hazardous polymerization. Conditions to Avoid:none Incompatibility:oxidizing agent Decomposition Products:carbon monoxide, carbon dioxide, titanium oxide and organic fumes. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Flammable solids, Organic, N.O.S. Hazard Class (CFR):4.1 Additional Hazard Class (CFR):NA Packaging Group (CFR):II UN ID Number (CFR):UN# 1325 Shipping Name (IATA):Flammable solid, Organic, N.O.S. Hazard Class (IATA):4.1 Additional Hazard Class (IATA):NA Packaging Group (IATA):II UN ID Number (IATA):UN# 1325 SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | T+ |
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Risk Phrases | 20/21/22-36/37/38-40 |
Safety Phrases | 26-36/37/39 |
RIDADR | UN3466 |
Packaging Group | II |
Hazard Class | 6.1 |