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18166-43-3

18166-43-3 structure
18166-43-3 structure

Name hydroxy-tris[(2-methylpropan-2-yl)oxy]silane
Synonyms Tri-tert-butyl hydrogen orthosilicate
MFCD00271024
Tri-t-butoxysilanol
tri-tert-butoxysilanol
Silicic acid (HSiO), tris(1,1-dimethylethyl) ester
Si(OH)(OtBu)3
tri-tert-butylsilanol
Tris(2-methyl-2-propanyl) hydrogen orthosilicate
(tert-(C4H9O)3)SiOH
tris-tert-butoxysilanol
Density 0.9±0.1 g/cm3
Boiling Point 263.4±23.0 °C at 760 mmHg
Melting Point 63-65ºC(lit.)
Molecular Formula C12H28O4Si
Molecular Weight 264.434
Flash Point 113.1±22.6 °C
Exact Mass 264.175690
PSA 47.92000
LogP 6.08
Vapour Pressure 0.0±1.2 mmHg at 25°C
Index of Refraction 1.436
Storage condition below 5° C

Section 1: Product Identification
Chemical Name:Tri-t-butoxysilanol (99.999%-Si) PURATREM
CAS Registry Number:18166-43-3
Formula:[(CH3)3CO]3SiOH
EINECS Number:none
Chemical Family:organosilicon compound
Synonym:Tris(tert-butoxy)silanol

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound18166-43-3100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure:Ingestion, inhalation, eyes
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
No information on long-term chronic effects. Contact with moisture, as resulting from human contact, will
Chronic Health Affects:
produce n-butanol which shows reproductive effects in animal studies.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit irritating fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non-combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Store in a tightly sealed container under an inert atmosphere of nitrogen or argon. Keep in a cool, dry,
Handling and Storage:
well-ventillated area.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white solid
Molecular Weight:264.43
Melting Point:63-65°C
Boiling Point:205-210C
Vapor Pressure:0.4mm @ 55?
Specific Gravity:0.89g/cc3
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:moisture sensitive
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:prolonged exposure to moisture
Incompatibility:strong oxidizing agents, strong acids and halogens
Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, butanol and silicon dioxide.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory
SARA (Title 313):Not reportable under SARA 313
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
Personal Protective Equipment Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
Risk Phrases 36/37/38
Safety Phrases 22-24/25
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2915900090

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18166-43-3 structure

18166-43-3

Literature: Inorganic Chemistry, , vol. 42, # 4 p. 1140 - 1150

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18166-43-3 structure

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Literature: Inorganic Chemistry, , vol. 42, # 4 p. 1140 - 1150

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18166-43-3 structure

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Literature: US2566956 , ;

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18166-43-3

Literature: Rec. Trav. chim., , vol. 61, p. 500 - 512

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18166-43-3 structure

18166-43-3

Literature: Recueil des Travaux Chimiques des Pays-Bas, , vol. 61, p. 502

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18166-43-3 structure

18166-43-3

Literature: Inorganic Chemistry, , vol. 42, # 4 p. 1140 - 1150

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18166-43-3 structure

18166-43-3

Literature: Inorganic Chemistry, , vol. 42, # 4 p. 1140 - 1150
HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%